Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms
With the using of a thermographic method reaction of oxidation of dibutylsulfide in a noctane 95,6 % concentrated solution of hydrogen peroxide in the mixture reactor with the propeller mixer is studied.It is established that dibutylsulfide oxidation by hydrogen peroxide in an ekvimoly-a...
Main Authors: | , |
---|---|
Format: | Article |
Language: | English |
Published: |
Kazan State Power Engineering University
2019-06-01
|
Series: | Известия высших учебных заведений: Проблемы энергетики |
Subjects: | |
Online Access: | https://www.energyret.ru/jour/article/view/916 |
id |
doaj-bf07a0fb04644c0699d824f9d5015fe0 |
---|---|
record_format |
Article |
spelling |
doaj-bf07a0fb04644c0699d824f9d5015fe02021-07-28T13:16:32ZengKazan State Power Engineering UniversityИзвестия высших учебных заведений: Проблемы энергетики1998-99032019-06-01213-43610.30724/1998-9903-2019-21-3-4-3-6567Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermogramsL. R. Gaynullina0V. P. Tutubalina1Kazan State Power Engineering UniversityKazan State Power Engineering UniversityWith the using of a thermographic method reaction of oxidation of dibutylsulfide in a noctane 95,6 % concentrated solution of hydrogen peroxide in the mixture reactor with the propeller mixer is studied.It is established that dibutylsulfide oxidation by hydrogen peroxide in an ekvimoly-arny ratio 1:1 at a temperature of 80 °C proceeds before formation of a dibutilsulfoksid, and at a ratio 1:2 and at a temperature of 100 °C – to a dibutilsulfon.The increase in amount of hydrogen peroxide and temperature is followed by for-mation of sour products – the sulfoniyevykh and sulfonew acids.By method of a gas-liquid chromatography it is proved that during oxidation of dibutylsulfide by hydrogen peroxide his destruction doesn't happen.https://www.energyret.ru/jour/article/view/916transformer oildibutylsulfideoxidationhydrogen peroxidethermogram |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
L. R. Gaynullina V. P. Tutubalina |
spellingShingle |
L. R. Gaynullina V. P. Tutubalina Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms Известия высших учебных заведений: Проблемы энергетики transformer oil dibutylsulfide oxidation hydrogen peroxide thermogram |
author_facet |
L. R. Gaynullina V. P. Tutubalina |
author_sort |
L. R. Gaynullina |
title |
Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
title_short |
Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
title_full |
Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
title_fullStr |
Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
title_full_unstemmed |
Dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
title_sort |
dibutylsulfide oxidation research the concentrated hydrogen peroxide solution by means of thermograms |
publisher |
Kazan State Power Engineering University |
series |
Известия высших учебных заведений: Проблемы энергетики |
issn |
1998-9903 |
publishDate |
2019-06-01 |
description |
With the using of a thermographic method reaction of oxidation of dibutylsulfide in a noctane 95,6 % concentrated solution of hydrogen peroxide in the mixture reactor with the propeller mixer is studied.It is established that dibutylsulfide oxidation by hydrogen peroxide in an ekvimoly-arny ratio 1:1 at a temperature of 80 °C proceeds before formation of a dibutilsulfoksid, and at a ratio 1:2 and at a temperature of 100 °C – to a dibutilsulfon.The increase in amount of hydrogen peroxide and temperature is followed by for-mation of sour products – the sulfoniyevykh and sulfonew acids.By method of a gas-liquid chromatography it is proved that during oxidation of dibutylsulfide by hydrogen peroxide his destruction doesn't happen. |
topic |
transformer oil dibutylsulfide oxidation hydrogen peroxide thermogram |
url |
https://www.energyret.ru/jour/article/view/916 |
work_keys_str_mv |
AT lrgaynullina dibutylsulfideoxidationresearchtheconcentratedhydrogenperoxidesolutionbymeansofthermograms AT vptutubalina dibutylsulfideoxidationresearchtheconcentratedhydrogenperoxidesolutionbymeansofthermograms |
_version_ |
1721275782533218304 |