[4,6-Dimethylpyrimidine-2(1H)-thione-κS]iodidobis(triphenylphosphane-κP)copper(I)

[4,6-Dimethylpyrimidine-2(1H)-thione-κS]iodidobis(triphenylphosphane-κP)copper(I)

In the mononuclear title complex, [CuI(C6H8N2S)(C18H15P)2], the CuI ion is in a slightly distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphane ligands, one S atom from a 4,6-dimethylpyrimidine-2(1H)-thione ligand and one iodide ion. There is an intramolecular...

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Main Authors: Chaveng Pakawatchai, Yupa Wattanakanjana, Patcharanan Choto, Ruthairat Nimthong
Format: Article
Language:English
Published: International Union of Crystallography 2012-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536812021010
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spelling doaj-c02d31379f314dfbaadb6518a1e5a03e2020-11-24T21:29:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-06-01686m773m77410.1107/S1600536812021010[4,6-Dimethylpyrimidine-2(1H)-thione-κS]iodidobis(triphenylphosphane-κP)copper(I)Chaveng PakawatchaiYupa WattanakanjanaPatcharanan ChotoRuthairat NimthongIn the mononuclear title complex, [CuI(C6H8N2S)(C18H15P)2], the CuI ion is in a slightly distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphane ligands, one S atom from a 4,6-dimethylpyrimidine-2(1H)-thione ligand and one iodide ion. There is an intramolecular N—H...I hydrogen bond. In the crystal, π–π stacking interactions [centroid–centroid distance = 3.594 (1) Å] are observed.http://scripts.iucr.org/cgi-bin/paper?S1600536812021010
collection DOAJ
language English
format Article
sources DOAJ
author Chaveng Pakawatchai
Yupa Wattanakanjana
Patcharanan Choto
Ruthairat Nimthong
spellingShingle Chaveng Pakawatchai
Yupa Wattanakanjana
Patcharanan Choto
Ruthairat Nimthong
[4,6-Dimethylpyrimidine-2(1H)-thione-κS]iodidobis(triphenylphosphane-κP)copper(I)
Acta Crystallographica Section E
author_facet Chaveng Pakawatchai
Yupa Wattanakanjana
Patcharanan Choto
Ruthairat Nimthong
author_sort Chaveng Pakawatchai
title [4,6-Dimethylpyrimidine-2(1H)-thione-κS]iodidobis(triphenylphosphane-κP)copper(I)
title_short [4,6-Dimethylpyrimidine-2(1H)-thione-κS]iodidobis(triphenylphosphane-κP)copper(I)
title_full [4,6-Dimethylpyrimidine-2(1H)-thione-κS]iodidobis(triphenylphosphane-κP)copper(I)
title_fullStr [4,6-Dimethylpyrimidine-2(1H)-thione-κS]iodidobis(triphenylphosphane-κP)copper(I)
title_full_unstemmed [4,6-Dimethylpyrimidine-2(1H)-thione-κS]iodidobis(triphenylphosphane-κP)copper(I)
title_sort [4,6-dimethylpyrimidine-2(1h)-thione-κs]iodidobis(triphenylphosphane-κp)copper(i)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-06-01
description In the mononuclear title complex, [CuI(C6H8N2S)(C18H15P)2], the CuI ion is in a slightly distorted tetrahedral coordination geometry formed by two P atoms from two triphenylphosphane ligands, one S atom from a 4,6-dimethylpyrimidine-2(1H)-thione ligand and one iodide ion. There is an intramolecular N—H...I hydrogen bond. In the crystal, π–π stacking interactions [centroid–centroid distance = 3.594 (1) Å] are observed.
url http://scripts.iucr.org/cgi-bin/paper?S1600536812021010
work_keys_str_mv AT chavengpakawatchai 46dimethylpyrimidine21hthioneamp954siodidobistriphenylphosphaneamp954pcopperi
AT yupawattanakanjana 46dimethylpyrimidine21hthioneamp954siodidobistriphenylphosphaneamp954pcopperi
AT patcharananchoto 46dimethylpyrimidine21hthioneamp954siodidobistriphenylphosphaneamp954pcopperi
AT ruthairatnimthong 46dimethylpyrimidine21hthioneamp954siodidobistriphenylphosphaneamp954pcopperi
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