Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate
The title compound, C15H13Br4NO4, was obtained via radical bromination reaction of ethyl 6,7-dimethoxy-2-methylquinoline-3-carboxylate and N-bromosuccinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar with a maxi...
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International Union of Crystallography
2010-08-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810029351 |
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doaj-c0a99c8aefd7469ea2806f8584162dd92020-11-25T03:27:03ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668o2155o215510.1107/S1600536810029351Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylateTing ZhouYu-hua LongDing-qiao YangHan-mei ZhangWen-ling WangThe title compound, C15H13Br4NO4, was obtained via radical bromination reaction of ethyl 6,7-dimethoxy-2-methylquinoline-3-carboxylate and N-bromosuccinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar with a maximum deviation from the mean plane of 0.035 (1) Å. The dihedral angle between the six-membered rings is 2.33 (2)°. The methoxy O atoms of the two neighboring methoxy groups are in-plane while their methyl C atoms are located on either side of the quinolyl ring plane at distances of −1.207 (1) and 1.223 (1) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536810029351 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Ting Zhou Yu-hua Long Ding-qiao Yang Han-mei Zhang Wen-ling Wang |
spellingShingle |
Ting Zhou Yu-hua Long Ding-qiao Yang Han-mei Zhang Wen-ling Wang Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate Acta Crystallographica Section E |
author_facet |
Ting Zhou Yu-hua Long Ding-qiao Yang Han-mei Zhang Wen-ling Wang |
author_sort |
Ting Zhou |
title |
Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate |
title_short |
Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate |
title_full |
Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate |
title_fullStr |
Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate |
title_full_unstemmed |
Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate |
title_sort |
ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2010-08-01 |
description |
The title compound, C15H13Br4NO4, was obtained via radical bromination reaction of ethyl 6,7-dimethoxy-2-methylquinoline-3-carboxylate and N-bromosuccinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar with a maximum deviation from the mean plane of 0.035 (1) Å. The dihedral angle between the six-membered rings is 2.33 (2)°. The methoxy O atoms of the two neighboring methoxy groups are in-plane while their methyl C atoms are located on either side of the quinolyl ring plane at distances of −1.207 (1) and 1.223 (1) Å. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810029351 |
work_keys_str_mv |
AT tingzhou ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate AT yuhualong ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate AT dingqiaoyang ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate AT hanmeizhang ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate AT wenlingwang ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate |
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1724589661228105728 |