Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate

Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate

The title compound, C15H13Br4NO4, was obtained via radical bromination reaction of ethyl 6,7-dimethoxy-2-methylquinoline-3-carboxylate and N-bromosuccinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar with a maxi...

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Main Authors: Ting Zhou, Yu-hua Long, Ding-qiao Yang, Han-mei Zhang, Wen-ling Wang
Format: Article
Language:English
Published: International Union of Crystallography 2010-08-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810029351
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spelling doaj-c0a99c8aefd7469ea2806f8584162dd92020-11-25T03:27:03ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668o2155o215510.1107/S1600536810029351Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylateTing ZhouYu-hua LongDing-qiao YangHan-mei ZhangWen-ling WangThe title compound, C15H13Br4NO4, was obtained via radical bromination reaction of ethyl 6,7-dimethoxy-2-methylquinoline-3-carboxylate and N-bromosuccinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar with a maximum deviation from the mean plane of 0.035 (1) Å. The dihedral angle between the six-membered rings is 2.33 (2)°. The methoxy O atoms of the two neighboring methoxy groups are in-plane while their methyl C atoms are located on either side of the quinolyl ring plane at distances of −1.207 (1) and 1.223 (1) Å. http://scripts.iucr.org/cgi-bin/paper?S1600536810029351
collection DOAJ
language English
format Article
sources DOAJ
author Ting Zhou
Yu-hua Long
Ding-qiao Yang
Han-mei Zhang
Wen-ling Wang
spellingShingle Ting Zhou
Yu-hua Long
Ding-qiao Yang
Han-mei Zhang
Wen-ling Wang
Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate
Acta Crystallographica Section E
author_facet Ting Zhou
Yu-hua Long
Ding-qiao Yang
Han-mei Zhang
Wen-ling Wang
author_sort Ting Zhou
title Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate
title_short Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate
title_full Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate
title_fullStr Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate
title_full_unstemmed Ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate
title_sort ethyl 5,8-dibromo-2-dibromomethyl-6,7-dimethoxyquinoline-3-carboxylate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-08-01
description The title compound, C15H13Br4NO4, was obtained via radical bromination reaction of ethyl 6,7-dimethoxy-2-methylquinoline-3-carboxylate and N-bromosuccinimide (NBS) in the presence of benzoyl peroxide (BPO) under photocatalytic conditions. The quinoline ring system is approximately planar with a maximum deviation from the mean plane of 0.035 (1) Å. The dihedral angle between the six-membered rings is 2.33 (2)°. The methoxy O atoms of the two neighboring methoxy groups are in-plane while their methyl C atoms are located on either side of the quinolyl ring plane at distances of −1.207 (1) and 1.223 (1) Å.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810029351
work_keys_str_mv AT tingzhou ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate
AT yuhualong ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate
AT dingqiaoyang ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate
AT hanmeizhang ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate
AT wenlingwang ethyl58dibromo2dibromomethyl67dimethoxyquinoline3carboxylate
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