Crystal structure of 2-{(E)-[(2-hydroxyphenyl)iminiumyl]methyl}-4-methylphenolate

Crystal structure of 2-{(E)-[(2-hydroxyphenyl)iminiumyl]methyl}-4-methylphenolate

The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N—H...O hydrogen bond generate S(6) and S(5) loops. In the crystal,...

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Bibliographic Details
Main Authors: Suresh Shalini, C. R. Girija, Mukesh M. Jotani, C. D. Sathish, T. V. Venkatesha
Format: Article
Language:English
Published: International Union of Crystallography 2015-05-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
Schiff base
N-(salicylidene)aniline
zwitterion
hydrogen bonding
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989015006374
Description
Summary:The title compound, C14H13NO2, exists as a zwitterion in the solid state, with the H atom of the phenol group transferred to the imine N atom. The dihedral angle between the planes of the benzene rings is 10.13 (9)°. Intramolecular N—H...O hydrogen bond generate S(6) and S(5) loops. In the crystal, molecules are connected by O—H...O hydrogen bonds, generating C(9) chains propagating in the [010] direction.
ISSN:2056-9890

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