What is a surface excess?

J. Willard Gibbs in his pioneering work on the influence of surfaces discontinuity upon the equilibrium of heterogene-ous masses suggested for the measurement of the quantities of a system a geometrical surface dividing the interfacial layer. Surface excess is the difference between the amount of a...

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Bibliographic Details
Main Author: A. Ch. Mitropoulos
Format: Article
Language:English
Published: Eastern Macedonia and Thrace Institute of Technology 2008-01-01
Series:Journal of Engineering Science and Technology Review
Subjects:
Online Access:http://www.jestr.org/downloads/volume1/fulltext1.pdf
Description
Summary:J. Willard Gibbs in his pioneering work on the influence of surfaces discontinuity upon the equilibrium of heterogene-ous masses suggested for the measurement of the quantities of a system a geometrical surface dividing the interfacial layer. Surface excess is the difference between the amount of a component actually present in the system, and that which would be present in a reference system if the bulk concentration in the adjoining phases were maintained up to the arbitrary chosen but precisely determined in position dividing surface.
ISSN:1791-2377