Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans
Successive [2+4] cycloadditions of arynes and isobenzofurans by site-selective halogen-lithium exchange of 1,2-dihaloarenes were developed, allowing the rapid construction of polycyclic compounds which serve as a useful synthetic intermediates for the preparation of various polyacene derivatives.
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| Format: | Article |
| Language: | English |
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MDPI AG
2015-10-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/20/10/19449 |
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Article |
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doaj-c331f82d6a6a417986ecdf269072be7f2020-11-25T00:24:13ZengMDPI AGMolecules1420-30492015-10-012010194491946210.3390/molecules201019449molecules201019449Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and IsobenzofuransShohei Eda0Toshiyuki Hamura1Department of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, JapanDepartment of Applied Chemistry for Environment, School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, JapanSuccessive [2+4] cycloadditions of arynes and isobenzofurans by site-selective halogen-lithium exchange of 1,2-dihaloarenes were developed, allowing the rapid construction of polycyclic compounds which serve as a useful synthetic intermediates for the preparation of various polyacene derivatives.http://www.mdpi.com/1420-3049/20/10/19449aryneisobenzofuran[2+4] cycloaddition1,2-dihaloarenespolyacenehalogen-lithium exchange |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Shohei Eda Toshiyuki Hamura |
| spellingShingle |
Shohei Eda Toshiyuki Hamura Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans Molecules aryne isobenzofuran [2+4] cycloaddition 1,2-dihaloarenes polyacene halogen-lithium exchange |
| author_facet |
Shohei Eda Toshiyuki Hamura |
| author_sort |
Shohei Eda |
| title |
Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans |
| title_short |
Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans |
| title_full |
Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans |
| title_fullStr |
Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans |
| title_full_unstemmed |
Selective Halogen-Lithium Exchange of 1,2-Dihaloarenes for Successive [2+4] Cycloadditions of Arynes and Isobenzofurans |
| title_sort |
selective halogen-lithium exchange of 1,2-dihaloarenes for successive [2+4] cycloadditions of arynes and isobenzofurans |
| publisher |
MDPI AG |
| series |
Molecules |
| issn |
1420-3049 |
| publishDate |
2015-10-01 |
| description |
Successive [2+4] cycloadditions of arynes and isobenzofurans by site-selective halogen-lithium exchange of 1,2-dihaloarenes were developed, allowing the rapid construction of polycyclic compounds which serve as a useful synthetic intermediates for the preparation of various polyacene derivatives. |
| topic |
aryne isobenzofuran [2+4] cycloaddition 1,2-dihaloarenes polyacene halogen-lithium exchange |
| url |
http://www.mdpi.com/1420-3049/20/10/19449 |
| work_keys_str_mv |
AT shoheieda selectivehalogenlithiumexchangeof12dihaloarenesforsuccessive24cycloadditionsofarynesandisobenzofurans AT toshiyukihamura selectivehalogenlithiumexchangeof12dihaloarenesforsuccessive24cycloadditionsofarynesandisobenzofurans |
| _version_ |
1725353200526032896 |