Di-μ-chlorido-bis{aquachlorido[3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole-κ2N1,N5]manganese(II)}

Di-μ-chlorido-bis{aquachlorido[3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole-κ2N1,N5]manganese(II)}

In the centrosymmetric dinuclear title compound, [Mn2Cl4(C15H14N4)2(H2O)2], the MnII atom is coordinated by an N,N′-bidentate ligand, a water molecule, a terminal chloride ion and two bridging chloride ions in a distorted MnN2OCl3 octahedral geometry. The Mn...Mn separation is 3.6563&#...

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Main Authors: Xiaoming Zhang, Chunyi Liu, Ixaoning Gong, Zuoxiang Wang
Format: Article
Language:English
Published: International Union of Crystallography 2009-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808044103
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spelling doaj-c3fcd827b8194d0a979b37984a9872a52020-11-25T02:46:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652m157m15710.1107/S1600536808044103Di-μ-chlorido-bis{aquachlorido[3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole-κ2N1,N5]manganese(II)}Xiaoming ZhangChunyi LiuIxaoning GongZuoxiang WangIn the centrosymmetric dinuclear title compound, [Mn2Cl4(C15H14N4)2(H2O)2], the MnII atom is coordinated by an N,N′-bidentate ligand, a water molecule, a terminal chloride ion and two bridging chloride ions in a distorted MnN2OCl3 octahedral geometry. The Mn...Mn separation is 3.6563 (9) Å. In the crystal structure, O—H...N and O—H...Cl hydrogen bonds help to establish the packing.http://scripts.iucr.org/cgi-bin/paper?S1600536808044103
collection DOAJ
language English
format Article
sources DOAJ
author Xiaoming Zhang
Chunyi Liu
Ixaoning Gong
Zuoxiang Wang
spellingShingle Xiaoming Zhang
Chunyi Liu
Ixaoning Gong
Zuoxiang Wang
Di-μ-chlorido-bis{aquachlorido[3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole-κ2N1,N5]manganese(II)}
Acta Crystallographica Section E
author_facet Xiaoming Zhang
Chunyi Liu
Ixaoning Gong
Zuoxiang Wang
author_sort Xiaoming Zhang
title Di-μ-chlorido-bis{aquachlorido[3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole-κ2N1,N5]manganese(II)}
title_short Di-μ-chlorido-bis{aquachlorido[3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole-κ2N1,N5]manganese(II)}
title_full Di-μ-chlorido-bis{aquachlorido[3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole-κ2N1,N5]manganese(II)}
title_fullStr Di-μ-chlorido-bis{aquachlorido[3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole-κ2N1,N5]manganese(II)}
title_full_unstemmed Di-μ-chlorido-bis{aquachlorido[3-ethyl-4-phenyl-5-(2-pyridyl)-4H-1,2,4-triazole-κ2N1,N5]manganese(II)}
title_sort di-μ-chlorido-bis{aquachlorido[3-ethyl-4-phenyl-5-(2-pyridyl)-4h-1,2,4-triazole-κ2n1,n5]manganese(ii)}
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-02-01
description In the centrosymmetric dinuclear title compound, [Mn2Cl4(C15H14N4)2(H2O)2], the MnII atom is coordinated by an N,N′-bidentate ligand, a water molecule, a terminal chloride ion and two bridging chloride ions in a distorted MnN2OCl3 octahedral geometry. The Mn...Mn separation is 3.6563 (9) Å. In the crystal structure, O—H...N and O—H...Cl hydrogen bonds help to establish the packing.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808044103
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AT chunyiliu di956chloridobisaquachlorido3ethyl4phenyl52pyridyl4h124triazole9542n1n5manganeseii
AT ixaoninggong di956chloridobisaquachlorido3ethyl4phenyl52pyridyl4h124triazole9542n1n5manganeseii
AT zuoxiangwang di956chloridobisaquachlorido3ethyl4phenyl52pyridyl4h124triazole9542n1n5manganeseii
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