N-[2-(4-Methyl-2-quinolyl)phenyl]acetamide: a P1 structure with Z = 4
The title compound, C18H16N2O, crystallizes in the triclinic space group P1, with four independent molecules in the asymmetric unit wherein two molecules have an irregular -ac, -ac, +ap conformation (ap, antiperiplanar; ac, anticlinal), while the other molecules exhibit a different, +ac, +ac, +ap co...
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International Union of Crystallography
2010-08-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810027650 |
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doaj-c42f0d50010e4021829afe97cbd8607f2020-11-25T02:14:20ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-08-01668o2043o204410.1107/S1600536810027650N-[2-(4-Methyl-2-quinolyl)phenyl]acetamide: a P1 structure with Z = 4F. Nawaz KhanS. Mohana RoopanN. MalathiVenkatesha R. HathwarMehmet AkkurtThe title compound, C18H16N2O, crystallizes in the triclinic space group P1, with four independent molecules in the asymmetric unit wherein two molecules have an irregular -ac, -ac, +ap conformation (ap, antiperiplanar; ac, anticlinal), while the other molecules exhibit a different, +ac, +ac, +ap conformation. The planar (r.m.s. deviation = 0.006 Å in each of the four molecules) quinoline ring systems of the four molecules are oriented at dihedral angles of 32.8 (2), 33.4 (2), 31.7 (2) and 32.3 (2)° with respect to the benzene rings. Intramolecular N—H...N interactions occur in all four independent molecules. The crystal packing is stabilized by intermolecular N—H...O and C—H...O hydrogen bonds, and are further consolidated by C—H...π and π–π stacking interactions [centroid–centroid distances = 3.728 (3), 3.722 (3), 3.758 (3) and 3.705 (3) Å]. http://scripts.iucr.org/cgi-bin/paper?S1600536810027650 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
F. Nawaz Khan S. Mohana Roopan N. Malathi Venkatesha R. Hathwar Mehmet Akkurt |
spellingShingle |
F. Nawaz Khan S. Mohana Roopan N. Malathi Venkatesha R. Hathwar Mehmet Akkurt N-[2-(4-Methyl-2-quinolyl)phenyl]acetamide: a P1 structure with Z = 4 Acta Crystallographica Section E |
author_facet |
F. Nawaz Khan S. Mohana Roopan N. Malathi Venkatesha R. Hathwar Mehmet Akkurt |
author_sort |
F. Nawaz Khan |
title |
N-[2-(4-Methyl-2-quinolyl)phenyl]acetamide: a P1 structure with Z = 4 |
title_short |
N-[2-(4-Methyl-2-quinolyl)phenyl]acetamide: a P1 structure with Z = 4 |
title_full |
N-[2-(4-Methyl-2-quinolyl)phenyl]acetamide: a P1 structure with Z = 4 |
title_fullStr |
N-[2-(4-Methyl-2-quinolyl)phenyl]acetamide: a P1 structure with Z = 4 |
title_full_unstemmed |
N-[2-(4-Methyl-2-quinolyl)phenyl]acetamide: a P1 structure with Z = 4 |
title_sort |
n-[2-(4-methyl-2-quinolyl)phenyl]acetamide: a p1 structure with z = 4 |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2010-08-01 |
description |
The title compound, C18H16N2O, crystallizes in the triclinic space group P1, with four independent molecules in the asymmetric unit wherein two molecules have an irregular -ac, -ac, +ap conformation (ap, antiperiplanar; ac, anticlinal), while the other molecules exhibit a different, +ac, +ac, +ap conformation. The planar (r.m.s. deviation = 0.006 Å in each of the four molecules) quinoline ring systems of the four molecules are oriented at dihedral angles of 32.8 (2), 33.4 (2), 31.7 (2) and 32.3 (2)° with respect to the benzene rings. Intramolecular N—H...N interactions occur in all four independent molecules. The crystal packing is stabilized by intermolecular N—H...O and C—H...O hydrogen bonds, and are further consolidated by C—H...π and π–π stacking interactions [centroid–centroid distances = 3.728 (3), 3.722 (3), 3.758 (3) and 3.705 (3) Å]. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536810027650 |
work_keys_str_mv |
AT fnawazkhan n24methyl2quinolylphenylacetamideap1structurewithz4 AT smohanaroopan n24methyl2quinolylphenylacetamideap1structurewithz4 AT nmalathi n24methyl2quinolylphenylacetamideap1structurewithz4 AT venkatesharhathwar n24methyl2quinolylphenylacetamideap1structurewithz4 AT mehmetakkurt n24methyl2quinolylphenylacetamideap1structurewithz4 |
_version_ |
1724900135815610368 |