Statistical evaluation of fluoride contamination in groundwater resources of Santiago del Estero Province, Argentina
This study investigates the suitability of statistical techniques for evaluating the fluoride content and the groundwater quality from Robles Department (RD) and Banda Department (BD) in Santiago del Estero (Argentina). For the original statistical study, evaluation of nine parameters (fluoride, pH,...
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doaj-c4556b004b41482eb93fe59a04e7dc082020-11-25T03:10:19ZengElsevierGeoscience Frontiers1674-98712020-11-0111621972205Statistical evaluation of fluoride contamination in groundwater resources of Santiago del Estero Province, ArgentinaK. Rondano Gómez0C.E. López Pasquali1G. Paniagua González2P. Fernández Hernando3R.M. Garcinuño Martínez4Departamento de Ciencias Básicas, Facultad de Ciencias Forestales, Universidad Nacional de Santiago Del Estero, Argentina; Departamento de Ciencias Analíticas, Facultad de Ciencias, Universidad Nacional de Educación a Distancia, SpainDepartamento de Química Analítica, Facultad de Agronomía y Agroindustrias, Universidad Nacional de Santiago Del Estero, ArgentinaDepartamento de Ciencias Analíticas, Facultad de Ciencias, Universidad Nacional de Educación a Distancia, Spain; Corresponding author. C/ Senda del Rey No. 9, 28040, Madrid, Spain.Departamento de Ciencias Analíticas, Facultad de Ciencias, Universidad Nacional de Educación a Distancia, SpainDepartamento de Ciencias Analíticas, Facultad de Ciencias, Universidad Nacional de Educación a Distancia, SpainThis study investigates the suitability of statistical techniques for evaluating the fluoride content and the groundwater quality from Robles Department (RD) and Banda Department (BD) in Santiago del Estero (Argentina). For the original statistical study, evaluation of nine parameters (fluoride, pH, conductivity, atmospheric and water temperature, total dissolved solids, chloride, hardness, and alkalinity) of 110 collected underground water samples from 23 dispersed rural areas was proposed. Groundwater samples were obtained by sampling taken from wells at different depths. Fluoride levels were determined by a standard colorimetric method in two seasonal periods, the dry (from April to September) and rainy (from October to March) period. The analytical results obtained for physicochemical parameters such as pH, total dissolved solids (TDS), and temperature does not reveal any notable difference between the rainy and dry seasons studied. In both seasons, the atmospheric temperature average was 22 °C. With respect to fluoride content, approximately 50% of the analysed groundwater samples exceeded the limit established by current legislation (1.0 mg/L), obtaining concentration levels in the range of 0.01–2.80 mg/L. This study demonstrates the usefulness of the univariate statistical method (quartiles calculation, interquartile range IQR), multivariate principal component analysis (PCA), and cluster analysis to establish a better understanding of the state of the contamination of the waters in the region studied.http://www.sciencedirect.com/science/article/pii/S1674987120300670Source water protectionSantiago del EsteroMultivariate statistical analysisFluorideSpectrophotometry |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
K. Rondano Gómez C.E. López Pasquali G. Paniagua González P. Fernández Hernando R.M. Garcinuño Martínez |
spellingShingle |
K. Rondano Gómez C.E. López Pasquali G. Paniagua González P. Fernández Hernando R.M. Garcinuño Martínez Statistical evaluation of fluoride contamination in groundwater resources of Santiago del Estero Province, Argentina Geoscience Frontiers Source water protection Santiago del Estero Multivariate statistical analysis Fluoride Spectrophotometry |
author_facet |
K. Rondano Gómez C.E. López Pasquali G. Paniagua González P. Fernández Hernando R.M. Garcinuño Martínez |
author_sort |
K. Rondano Gómez |
title |
Statistical evaluation of fluoride contamination in groundwater resources of Santiago del Estero Province, Argentina |
title_short |
Statistical evaluation of fluoride contamination in groundwater resources of Santiago del Estero Province, Argentina |
title_full |
Statistical evaluation of fluoride contamination in groundwater resources of Santiago del Estero Province, Argentina |
title_fullStr |
Statistical evaluation of fluoride contamination in groundwater resources of Santiago del Estero Province, Argentina |
title_full_unstemmed |
Statistical evaluation of fluoride contamination in groundwater resources of Santiago del Estero Province, Argentina |
title_sort |
statistical evaluation of fluoride contamination in groundwater resources of santiago del estero province, argentina |
publisher |
Elsevier |
series |
Geoscience Frontiers |
issn |
1674-9871 |
publishDate |
2020-11-01 |
description |
This study investigates the suitability of statistical techniques for evaluating the fluoride content and the groundwater quality from Robles Department (RD) and Banda Department (BD) in Santiago del Estero (Argentina). For the original statistical study, evaluation of nine parameters (fluoride, pH, conductivity, atmospheric and water temperature, total dissolved solids, chloride, hardness, and alkalinity) of 110 collected underground water samples from 23 dispersed rural areas was proposed. Groundwater samples were obtained by sampling taken from wells at different depths. Fluoride levels were determined by a standard colorimetric method in two seasonal periods, the dry (from April to September) and rainy (from October to March) period. The analytical results obtained for physicochemical parameters such as pH, total dissolved solids (TDS), and temperature does not reveal any notable difference between the rainy and dry seasons studied. In both seasons, the atmospheric temperature average was 22 °C. With respect to fluoride content, approximately 50% of the analysed groundwater samples exceeded the limit established by current legislation (1.0 mg/L), obtaining concentration levels in the range of 0.01–2.80 mg/L. This study demonstrates the usefulness of the univariate statistical method (quartiles calculation, interquartile range IQR), multivariate principal component analysis (PCA), and cluster analysis to establish a better understanding of the state of the contamination of the waters in the region studied. |
topic |
Source water protection Santiago del Estero Multivariate statistical analysis Fluoride Spectrophotometry |
url |
http://www.sciencedirect.com/science/article/pii/S1674987120300670 |
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