Bis(4-fluoroanilinium) tetrachloridocuprate(II)

Bis(4-fluoroanilinium) tetrachloridocuprate(II)

The crystal structure of the title compound, (C6H7FN)2[CuCl4], consists of parallel two-dimensional perovskite-type layers of corner-sharing CuCl6 octahedra. These are bonded together via N—H...Cl hydrogen bonds from the 4-fluoroanilinium chains, which are almost perpendicular to the l...

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Main Authors: Min Min Zhao, Ping Ping Shi
Format: Article
Language:English
Published: International Union of Crystallography 2010-06-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810017289
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spelling doaj-c48fe9a931c64aee9ab9b2bbf309951e2020-11-25T01:35:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m656m65610.1107/S1600536810017289Bis(4-fluoroanilinium) tetrachloridocuprate(II)Min Min ZhaoPing Ping ShiThe crystal structure of the title compound, (C6H7FN)2[CuCl4], consists of parallel two-dimensional perovskite-type layers of corner-sharing CuCl6 octahedra. These are bonded together via N—H...Cl hydrogen bonds from the 4-fluoroanilinium chains, which are almost perpendicular to the layers. The CuCl4 dianions have two short Cu—Cl bonds [2.2657 (15) and 2.2884 (13) Å] and two longer bonds [2.8868 (15) Å], giving highly Jahn–Teller-distorted CuCl6 octahedra. The Cu atoms are situated on crystallographic centers of inversion. http://scripts.iucr.org/cgi-bin/paper?S1600536810017289
collection DOAJ
language English
format Article
sources DOAJ
author Min Min Zhao
Ping Ping Shi
spellingShingle Min Min Zhao
Ping Ping Shi
Bis(4-fluoroanilinium) tetrachloridocuprate(II)
Acta Crystallographica Section E
author_facet Min Min Zhao
Ping Ping Shi
author_sort Min Min Zhao
title Bis(4-fluoroanilinium) tetrachloridocuprate(II)
title_short Bis(4-fluoroanilinium) tetrachloridocuprate(II)
title_full Bis(4-fluoroanilinium) tetrachloridocuprate(II)
title_fullStr Bis(4-fluoroanilinium) tetrachloridocuprate(II)
title_full_unstemmed Bis(4-fluoroanilinium) tetrachloridocuprate(II)
title_sort bis(4-fluoroanilinium) tetrachloridocuprate(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-06-01
description The crystal structure of the title compound, (C6H7FN)2[CuCl4], consists of parallel two-dimensional perovskite-type layers of corner-sharing CuCl6 octahedra. These are bonded together via N—H...Cl hydrogen bonds from the 4-fluoroanilinium chains, which are almost perpendicular to the layers. The CuCl4 dianions have two short Cu—Cl bonds [2.2657 (15) and 2.2884 (13) Å] and two longer bonds [2.8868 (15) Å], giving highly Jahn–Teller-distorted CuCl6 octahedra. The Cu atoms are situated on crystallographic centers of inversion.
url http://scripts.iucr.org/cgi-bin/paper?S1600536810017289
work_keys_str_mv AT minminzhao bis4fluoroaniliniumtetrachloridocuprateii
AT pingpingshi bis4fluoroaniliniumtetrachloridocuprateii
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