A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor
Solid state Pt(II)-pincer complexes exhibiting vapochromic responses show promise for chemical sensing applications, but their slow responses typically limit their utility. Here, Raithby and colleagues design a Pt(II)-pincer complex with a subsecond, highly-selective vapochromic response to water an...
| Main Authors: | , , , , , , , , , , , , , , , , , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Nature Publishing Group
2017-11-01
|
| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-017-01941-2 |
| id |
doaj-c4ef5d3316404f079cffce8731ae28b0 |
|---|---|
| record_format |
Article |
| spelling |
doaj-c4ef5d3316404f079cffce8731ae28b02021-05-11T07:05:17ZengNature Publishing GroupNature Communications2041-17232017-11-01811910.1038/s41467-017-01941-2A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensorM. J. Bryant0J. M. Skelton1L. E. Hatcher2C. Stubbs3E. Madrid4A. R. Pallipurath5L. H. Thomas6C. H. Woodall7J. Christensen8S. Fuertes9T. P. Robinson10C. M. Beavers11S. J. Teat12M. R. Warren13F. Pradaux-Caggiano14A. Walsh15F. Marken16D. R. Carbery17S. C. Parker18N. B. McKeown19R. Malpass-Evans20M. Carta21P. R. Raithby22Department of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownResearch Complex at Harwell, Rutherford Appleton Laboratory, Harwell OxfordDepartment of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownAdvanced Light Source, Lawrence Berkeley National LaboratoryAdvanced Light Source, Lawrence Berkeley National LaboratoryBeamline I19, Diamond Light Source, Harwell Science and Innovation CampusDepartment of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownDepartment of Chemistry, University of Bath, Claverton DownEastChem, School of Chemistry, University of EdinburghEastChem, School of Chemistry, University of EdinburghEastChem, School of Chemistry, University of EdinburghDepartment of Chemistry, University of Bath, Claverton DownSolid state Pt(II)-pincer complexes exhibiting vapochromic responses show promise for chemical sensing applications, but their slow responses typically limit their utility. Here, Raithby and colleagues design a Pt(II)-pincer complex with a subsecond, highly-selective vapochromic response to water and methanol.https://doi.org/10.1038/s41467-017-01941-2 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
M. J. Bryant J. M. Skelton L. E. Hatcher C. Stubbs E. Madrid A. R. Pallipurath L. H. Thomas C. H. Woodall J. Christensen S. Fuertes T. P. Robinson C. M. Beavers S. J. Teat M. R. Warren F. Pradaux-Caggiano A. Walsh F. Marken D. R. Carbery S. C. Parker N. B. McKeown R. Malpass-Evans M. Carta P. R. Raithby |
| spellingShingle |
M. J. Bryant J. M. Skelton L. E. Hatcher C. Stubbs E. Madrid A. R. Pallipurath L. H. Thomas C. H. Woodall J. Christensen S. Fuertes T. P. Robinson C. M. Beavers S. J. Teat M. R. Warren F. Pradaux-Caggiano A. Walsh F. Marken D. R. Carbery S. C. Parker N. B. McKeown R. Malpass-Evans M. Carta P. R. Raithby A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor Nature Communications |
| author_facet |
M. J. Bryant J. M. Skelton L. E. Hatcher C. Stubbs E. Madrid A. R. Pallipurath L. H. Thomas C. H. Woodall J. Christensen S. Fuertes T. P. Robinson C. M. Beavers S. J. Teat M. R. Warren F. Pradaux-Caggiano A. Walsh F. Marken D. R. Carbery S. C. Parker N. B. McKeown R. Malpass-Evans M. Carta P. R. Raithby |
| author_sort |
M. J. Bryant |
| title |
A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor |
| title_short |
A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor |
| title_full |
A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor |
| title_fullStr |
A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor |
| title_full_unstemmed |
A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor |
| title_sort |
rapidly-reversible absorptive and emissive vapochromic pt(ii) pincer-based chemical sensor |
| publisher |
Nature Publishing Group |
| series |
Nature Communications |
| issn |
2041-1723 |
| publishDate |
2017-11-01 |
| description |
Solid state Pt(II)-pincer complexes exhibiting vapochromic responses show promise for chemical sensing applications, but their slow responses typically limit their utility. Here, Raithby and colleagues design a Pt(II)-pincer complex with a subsecond, highly-selective vapochromic response to water and methanol. |
| url |
https://doi.org/10.1038/s41467-017-01941-2 |
| work_keys_str_mv |
AT mjbryant arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT jmskelton arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT lehatcher arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT cstubbs arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT emadrid arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT arpallipurath arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT lhthomas arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT chwoodall arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT jchristensen arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT sfuertes arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT tprobinson arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT cmbeavers arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT sjteat arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT mrwarren arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT fpradauxcaggiano arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT awalsh arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT fmarken arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT drcarbery arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT scparker arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT nbmckeown arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT rmalpassevans arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT mcarta arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT prraithby arapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT mjbryant rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT jmskelton rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT lehatcher rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT cstubbs rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT emadrid rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT arpallipurath rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT lhthomas rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT chwoodall rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT jchristensen rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT sfuertes rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT tprobinson rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT cmbeavers rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT sjteat rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT mrwarren rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT fpradauxcaggiano rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT awalsh rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT fmarken rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT drcarbery rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT scparker rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT nbmckeown rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT rmalpassevans rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT mcarta rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor AT prraithby rapidlyreversibleabsorptiveandemissivevapochromicptiipincerbasedchemicalsensor |
| _version_ |
1721452844439044096 |