Structural Representation of Organometallics and Coordination Compounds and a Recommended Representation by Use of Dashed Lines

By using broken lines to represent coordination interactions in organometallic and other coordinated compounds, we can draw structures satisfying the valencies of the atoms present. These broken lines should be used to replace many false single covalent bonds now used to depict organometallic and co...

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Bibliographic Details
Main Author: Shu-Kun Lin
Format: Article
Language:English
Published: MDPI AG 2002-12-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/7/11/848/
Description
Summary:By using broken lines to represent coordination interactions in organometallic and other coordinated compounds, we can draw structures satisfying the valencies of the atoms present. These broken lines should be used to replace many false single covalent bonds now used to depict organometallic and coordinated compounds. Chemical drawing software should not recognize such broken lines as single covalent bonds and they should be ignored. An example of confusing and erroneous structural representation of organometallics and coordination compounds is discussed.
ISSN:1420-3049