Synthesis of Symmetrical and Non-symmetrical Diimines from Dimedone
Symmetrical and non-symmetrical diimines derived from dimedone were synthesized by the reaction of their corresponding enaminothiones with primary amines. The synthesized compounds were characterized using micro analytical data and NMR spectroscopy. Theoretical calculations by B3LYP/6-31G(d,p) level...
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| Language: | English |
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MDPI AG
2009-06-01
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| Series: | Molecules |
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| Online Access: | http://www.mdpi.com/1420-3049/14/6/2278/ |
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doaj-c73152e970d54985a4481ca214a99ddf2020-11-25T01:13:21ZengMDPI AGMolecules1420-30492009-06-011462278228510.3390/molecules14062278Synthesis of Symmetrical and Non-symmetrical Diimines from DimedoneIbrahim A. MusadBahjat A. SaeedSymmetrical and non-symmetrical diimines derived from dimedone were synthesized by the reaction of their corresponding enaminothiones with primary amines. The synthesized compounds were characterized using micro analytical data and NMR spectroscopy. Theoretical calculations by B3LYP/6-31G(d,p) level of theory show that the enolic form is the most stable within the possible tautomeric forms of the compounds. http://www.mdpi.com/1420-3049/14/6/2278/dimedonediiminesenaminothionesB3LYP/6-31G(dp) |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Ibrahim A. Musad Bahjat A. Saeed |
| spellingShingle |
Ibrahim A. Musad Bahjat A. Saeed Synthesis of Symmetrical and Non-symmetrical Diimines from Dimedone Molecules dimedone diimines enaminothiones B3LYP/6-31G(d p) |
| author_facet |
Ibrahim A. Musad Bahjat A. Saeed |
| author_sort |
Ibrahim A. Musad |
| title |
Synthesis of Symmetrical and Non-symmetrical Diimines from Dimedone |
| title_short |
Synthesis of Symmetrical and Non-symmetrical Diimines from Dimedone |
| title_full |
Synthesis of Symmetrical and Non-symmetrical Diimines from Dimedone |
| title_fullStr |
Synthesis of Symmetrical and Non-symmetrical Diimines from Dimedone |
| title_full_unstemmed |
Synthesis of Symmetrical and Non-symmetrical Diimines from Dimedone |
| title_sort |
synthesis of symmetrical and non-symmetrical diimines from dimedone |
| publisher |
MDPI AG |
| series |
Molecules |
| issn |
1420-3049 |
| publishDate |
2009-06-01 |
| description |
Symmetrical and non-symmetrical diimines derived from dimedone were synthesized by the reaction of their corresponding enaminothiones with primary amines. The synthesized compounds were characterized using micro analytical data and NMR spectroscopy. Theoretical calculations by B3LYP/6-31G(d,p) level of theory show that the enolic form is the most stable within the possible tautomeric forms of the compounds. |
| topic |
dimedone diimines enaminothiones B3LYP/6-31G(d p) |
| url |
http://www.mdpi.com/1420-3049/14/6/2278/ |
| work_keys_str_mv |
AT ibrahimamusad synthesisofsymmetricalandnonsymmetricaldiiminesfromdimedone AT bahjatasaeed synthesisofsymmetricalandnonsymmetricaldiiminesfromdimedone |
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1725162996782596096 |