Summary: | The use of lignin can be one of the methods of coke powder substitution in the agglomeration process. This article specifies the material research of lignin and the technological and ecological parameters of the agglomeration process in laboratory conditions using biomass lignin. The methodology of the Raman and infrared spectroscopy, representing a new approach in the analysis and assessment for the purposes of material characteristics for the agglomeration process, was applied to study the structure of carbonaceous matter. The material research of lignin has determined that its calorific value corresponds to ca. 80% of the calorific value of coke powder, while its reactivity is higher than that of the coke. Although the substitution of coke powder using different types of waste biomass (e.g., wood sawdust) in the production of the agglomerate is limited to the maximum of 8–15%, in case of lignin, more than 20% can be substituted, while the standard properties of the produced agglomerate are maintained. The lower emissions of sulfur and nitrogen oxides as well as the reduction of carbon footprint in the agglomeration process as a result of the so-called zero CO<sub>2</sub> balance in the formation and processing of the biomass represent its positive aspects. Based on the laboratory research of lignin, up to a 50% substitution of coke powder with this type of biomass can be predicted for the technology of agglomerate production in real operation.
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