Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate
Treatment of [Et4N]2[(edt)2Mo2S2(μ-S)2] (edt = ethanedithiolate) with two equivalents of Ag(CH3CN)4ClO4 in the presence of bis(diphenylphosphino)methane (dppm) ligand gives rise to the title tetranuclear cluster, [Ag2Mo2(C2H4S2)2S4(C25H22P2)2]·3C3H7NO. The complex molecule...
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International Union of Crystallography
2009-12-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809048648 |
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doaj-c77c774c94d9454e90fc58c2a58284522020-11-25T01:57:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1615m161510.1107/S1600536809048648Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvateXiu-Li YouXing-Cong WangTreatment of [Et4N]2[(edt)2Mo2S2(μ-S)2] (edt = ethanedithiolate) with two equivalents of Ag(CH3CN)4ClO4 in the presence of bis(diphenylphosphino)methane (dppm) ligand gives rise to the title tetranuclear cluster, [Ag2Mo2(C2H4S2)2S4(C25H22P2)2]·3C3H7NO. The complex molecule and one of the dimethylformamide (DMF) solvent molecules occupy special positions on a mirror plane. The molecular structure of the complex may be visualized as being built of [Mo2S2(μ-S)2(edt)2]2− dianions and [Ag2(dppm)2]2+ dications connected by two Ag—μ-Sedt and two Ag—μ4-S bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536809048648 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Xiu-Li You Xing-Cong Wang |
spellingShingle |
Xiu-Li You Xing-Cong Wang Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate Acta Crystallographica Section E |
author_facet |
Xiu-Li You Xing-Cong Wang |
author_sort |
Xiu-Li You |
title |
Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate |
title_short |
Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate |
title_full |
Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate |
title_fullStr |
Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate |
title_full_unstemmed |
Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate |
title_sort |
bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(v)disilver(i) dimethylformamide trisolvate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2009-12-01 |
description |
Treatment of [Et4N]2[(edt)2Mo2S2(μ-S)2] (edt = ethanedithiolate) with two equivalents of Ag(CH3CN)4ClO4 in the presence of bis(diphenylphosphino)methane (dppm) ligand gives rise to the title tetranuclear cluster, [Ag2Mo2(C2H4S2)2S4(C25H22P2)2]·3C3H7NO. The complex molecule and one of the dimethylformamide (DMF) solvent molecules occupy special positions on a mirror plane. The molecular structure of the complex may be visualized as being built of [Mo2S2(μ-S)2(edt)2]2− dianions and [Ag2(dppm)2]2+ dications connected by two Ag—μ-Sedt and two Ag—μ4-S bonds. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536809048648 |
work_keys_str_mv |
AT xiuliyou bisamp9562bisdiphenylphosphinomethanebisamp9562ethane12dithiolatoamp9564sulfidoamp9562sulfidodisulfidodimolybdenumvdisilveridimethylformamidetrisolvate AT xingcongwang bisamp9562bisdiphenylphosphinomethanebisamp9562ethane12dithiolatoamp9564sulfidoamp9562sulfidodisulfidodimolybdenumvdisilveridimethylformamidetrisolvate |
_version_ |
1724976768674168832 |