Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate

Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate

Treatment of [Et4N]2[(edt)2Mo2S2(μ-S)2] (edt = ethanedithiolate) with two equivalents of Ag(CH3CN)4ClO4 in the presence of bis(diphenylphosphino)methane (dppm) ligand gives rise to the title tetranuclear cluster, [Ag2Mo2(C2H4S2)2S4(C25H22P2)2]·3C3H7NO. The complex molecule...

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Bibliographic Details
Main Authors: Xiu-Li You, Xing-Cong Wang
Format: Article
Language:English
Published: International Union of Crystallography 2009-12-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809048648
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spelling doaj-c77c774c94d9454e90fc58c2a58284522020-11-25T01:57:02ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1615m161510.1107/S1600536809048648Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvateXiu-Li YouXing-Cong WangTreatment of [Et4N]2[(edt)2Mo2S2(μ-S)2] (edt = ethanedithiolate) with two equivalents of Ag(CH3CN)4ClO4 in the presence of bis(diphenylphosphino)methane (dppm) ligand gives rise to the title tetranuclear cluster, [Ag2Mo2(C2H4S2)2S4(C25H22P2)2]·3C3H7NO. The complex molecule and one of the dimethylformamide (DMF) solvent molecules occupy special positions on a mirror plane. The molecular structure of the complex may be visualized as being built of [Mo2S2(μ-S)2(edt)2]2− dianions and [Ag2(dppm)2]2+ dications connected by two Ag—μ-Sedt and two Ag—μ4-S bonds. http://scripts.iucr.org/cgi-bin/paper?S1600536809048648
collection DOAJ
language English
format Article
sources DOAJ
author Xiu-Li You
Xing-Cong Wang
spellingShingle Xiu-Li You
Xing-Cong Wang
Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate
Acta Crystallographica Section E
author_facet Xiu-Li You
Xing-Cong Wang
author_sort Xiu-Li You
title Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate
title_short Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate
title_full Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate
title_fullStr Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate
title_full_unstemmed Bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate
title_sort bis[μ2-bis(diphenylphosphino)methane]bis(μ2-ethane-1,2-dithiolato)-μ4-sulfido-μ2-sulfido-disulfidodimolybdenum(v)disilver(i) dimethylformamide trisolvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-12-01
description Treatment of [Et4N]2[(edt)2Mo2S2(μ-S)2] (edt = ethanedithiolate) with two equivalents of Ag(CH3CN)4ClO4 in the presence of bis(diphenylphosphino)methane (dppm) ligand gives rise to the title tetranuclear cluster, [Ag2Mo2(C2H4S2)2S4(C25H22P2)2]·3C3H7NO. The complex molecule and one of the dimethylformamide (DMF) solvent molecules occupy special positions on a mirror plane. The molecular structure of the complex may be visualized as being built of [Mo2S2(μ-S)2(edt)2]2− dianions and [Ag2(dppm)2]2+ dications connected by two Ag—μ-Sedt and two Ag—μ4-S bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809048648
work_keys_str_mv AT xiuliyou bisamp9562bisdiphenylphosphinomethanebisamp9562ethane12dithiolatoamp9564sulfidoamp9562sulfidodisulfidodimolybdenumvdisilveridimethylformamidetrisolvate
AT xingcongwang bisamp9562bisdiphenylphosphinomethanebisamp9562ethane12dithiolatoamp9564sulfidoamp9562sulfidodisulfidodimolybdenumvdisilveridimethylformamidetrisolvate
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