Development of method for determination of the kinetics constants of coal char gasification in pore diffusion regimes
In this paper, we developed a method for determining the kinetic constants of partially diffusion-controlled heterogeneous reactions in a porous sample of powder. Studies have been conducted on the experimental data of thermogravimetric analysis of carbon conversion in a stream of CO2, using a new m...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
EDP Sciences
2019-01-01
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| Series: | E3S Web of Conferences |
| Online Access: | https://www.e3s-conferences.org/articles/e3sconf/pdf/2019/40/e3sconf_esr2019_07007.pdf |
| Summary: | In this paper, we developed a method for determining the kinetic constants of partially diffusion-controlled heterogeneous reactions in a porous sample of powder. Studies have been conducted on the experimental data of thermogravimetric analysis of carbon conversion in a stream of CO2, using a new method of processing kinetic curves, to obtain updated values of the kinetic constants under conditions where widely used models are inappropriate. Data obtained can be used for a reliable assessment of the characteristics of the gasification process. |
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| ISSN: | 2267-1242 |