trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II)

trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II)

In the centrosymmetric title compound, [Ni(C6H4NO2)2(C22H34N6)], the NiII ion is bonded to the four secondary N atoms of the macrocyclic ligand in a square-planar fashion and two carboxylate O atoms of the isonicotinate ions in axial positions, resulting in a tetragonally distorted octahedron. An of...

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Main Authors: Kil Sik Min, Bong Gon Kim, Jeong Hyeong Han
Format: Article
Language:English
Published: International Union of Crystallography 2008-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808001116
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spelling doaj-c8717bf6b9674b2889c9bd7a45b871f52020-11-25T00:49:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-02-01642m366m36610.1107/S1600536808001116trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II)Kil Sik MinBong Gon KimJeong Hyeong HanIn the centrosymmetric title compound, [Ni(C6H4NO2)2(C22H34N6)], the NiII ion is bonded to the four secondary N atoms of the macrocyclic ligand in a square-planar fashion and two carboxylate O atoms of the isonicotinate ions in axial positions, resulting in a tetragonally distorted octahedron. An offset face-to-face π–π stacking interaction [centroid–centroid distance = 3.674(4) Å] and N—H...N and N—H...O hydrogen-bonding interactions give rise to a one-dimensional supramolecular structure in the solid state.http://scripts.iucr.org/cgi-bin/paper?S1600536808001116
collection DOAJ
language English
format Article
sources DOAJ
author Kil Sik Min
Bong Gon Kim
Jeong Hyeong Han
spellingShingle Kil Sik Min
Bong Gon Kim
Jeong Hyeong Han
trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II)
Acta Crystallographica Section E
author_facet Kil Sik Min
Bong Gon Kim
Jeong Hyeong Han
author_sort Kil Sik Min
title trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II)
title_short trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II)
title_full trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II)
title_fullStr trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II)
title_full_unstemmed trans-(1,8-Dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(II)
title_sort trans-(1,8-dibenzyl-1,3,6,8,10,13-hexaazacyclotetradecane)diisonicotinatonickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-02-01
description In the centrosymmetric title compound, [Ni(C6H4NO2)2(C22H34N6)], the NiII ion is bonded to the four secondary N atoms of the macrocyclic ligand in a square-planar fashion and two carboxylate O atoms of the isonicotinate ions in axial positions, resulting in a tetragonally distorted octahedron. An offset face-to-face π–π stacking interaction [centroid–centroid distance = 3.674(4) Å] and N—H...N and N—H...O hydrogen-bonding interactions give rise to a one-dimensional supramolecular structure in the solid state.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808001116
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AT bonggonkim trans18dibenzyl13681013hexaazacyclotetradecanediisonicotinatonickelii
AT jeonghyeonghan trans18dibenzyl13681013hexaazacyclotetradecanediisonicotinatonickelii
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