Application of Taguchi method and response surface methodology into the removal of malachite green and auramine-O by NaX nanozeolites
Abstract In the present study, the simultaneous removal of malachite green (MG) and auramine-O (AO) dyes from the aqueous solution by NaX nanozeolites in a batch system is investigated. Taguchi method and response surface methodology (RSM) were used to optimize and model dye removal conditions. In o...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Nature Publishing Group
2021-08-01
|
Series: | Scientific Reports |
Online Access: | https://doi.org/10.1038/s41598-021-95649-5 |
id |
doaj-c8884f6607504f65a1dbe98d3b93a03c |
---|---|
record_format |
Article |
spelling |
doaj-c8884f6607504f65a1dbe98d3b93a03c2021-08-08T11:24:41ZengNature Publishing GroupScientific Reports2045-23222021-08-0111111310.1038/s41598-021-95649-5Application of Taguchi method and response surface methodology into the removal of malachite green and auramine-O by NaX nanozeolitesSiroos Shojaei0Saeed Shojaei1Shahab S. Band2Amir Abbas Kazemzadeh Farizhandi3Milad Ghoroqi4Amir Mosavi5Department of Chemistry, Faculty of Sciences, University of Sistan and BaluchestanDepartment of Arid and Mountainous Regions Reclamation, Faculty of Natural Resources, University of TehranFuture Technology Research Center, National Yunlin University of Science and TechnologyComputer Science Department, Boise State UniversityDepartment of Civil Engineering, Islamic Azad UniversityJohn von Neumann Faculty of Informatics, Obuda UniversityAbstract In the present study, the simultaneous removal of malachite green (MG) and auramine-O (AO) dyes from the aqueous solution by NaX nanozeolites in a batch system is investigated. Taguchi method and response surface methodology (RSM) were used to optimize and model dye removal conditions. In order to do so, the effect of various factors (dyes concentration, sonication time, ionic strength, adsorbent dosage, temperature, and pH of the solution) on the amount of dye removal was evaluated by the Taguchi method. Then, the most important factors were chosen and modeled by the RSM method so as to reach the highest percentage of dye removal. The proposed quadratic models to remove both dyes were in good accordance with the actual experimental data. The maximum removal efficiencies of MG and AO dyes in optimal operating conditions were 99.07% and 99.61%, respectively. Also, the coefficients of determination (R2) for test data were 0.9983 and 0.9988 for MG and AO dyes, respectively. The reusability of NaX nanozeolites was evaluated during the adsorption process of MG and AO. The results showed that the adsorption efficiency decreases very little up to five cycles. Moreover, NaX nanozeolites were also applied as adsorbents to remove MG and AO from environmental water samples, and more than 98.1% of both dyes were removed from the solution in optimal conditions.https://doi.org/10.1038/s41598-021-95649-5 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Siroos Shojaei Saeed Shojaei Shahab S. Band Amir Abbas Kazemzadeh Farizhandi Milad Ghoroqi Amir Mosavi |
spellingShingle |
Siroos Shojaei Saeed Shojaei Shahab S. Band Amir Abbas Kazemzadeh Farizhandi Milad Ghoroqi Amir Mosavi Application of Taguchi method and response surface methodology into the removal of malachite green and auramine-O by NaX nanozeolites Scientific Reports |
author_facet |
Siroos Shojaei Saeed Shojaei Shahab S. Band Amir Abbas Kazemzadeh Farizhandi Milad Ghoroqi Amir Mosavi |
author_sort |
Siroos Shojaei |
title |
Application of Taguchi method and response surface methodology into the removal of malachite green and auramine-O by NaX nanozeolites |
title_short |
Application of Taguchi method and response surface methodology into the removal of malachite green and auramine-O by NaX nanozeolites |
title_full |
Application of Taguchi method and response surface methodology into the removal of malachite green and auramine-O by NaX nanozeolites |
title_fullStr |
Application of Taguchi method and response surface methodology into the removal of malachite green and auramine-O by NaX nanozeolites |
title_full_unstemmed |
Application of Taguchi method and response surface methodology into the removal of malachite green and auramine-O by NaX nanozeolites |
title_sort |
application of taguchi method and response surface methodology into the removal of malachite green and auramine-o by nax nanozeolites |
publisher |
Nature Publishing Group |
series |
Scientific Reports |
issn |
2045-2322 |
publishDate |
2021-08-01 |
description |
Abstract In the present study, the simultaneous removal of malachite green (MG) and auramine-O (AO) dyes from the aqueous solution by NaX nanozeolites in a batch system is investigated. Taguchi method and response surface methodology (RSM) were used to optimize and model dye removal conditions. In order to do so, the effect of various factors (dyes concentration, sonication time, ionic strength, adsorbent dosage, temperature, and pH of the solution) on the amount of dye removal was evaluated by the Taguchi method. Then, the most important factors were chosen and modeled by the RSM method so as to reach the highest percentage of dye removal. The proposed quadratic models to remove both dyes were in good accordance with the actual experimental data. The maximum removal efficiencies of MG and AO dyes in optimal operating conditions were 99.07% and 99.61%, respectively. Also, the coefficients of determination (R2) for test data were 0.9983 and 0.9988 for MG and AO dyes, respectively. The reusability of NaX nanozeolites was evaluated during the adsorption process of MG and AO. The results showed that the adsorption efficiency decreases very little up to five cycles. Moreover, NaX nanozeolites were also applied as adsorbents to remove MG and AO from environmental water samples, and more than 98.1% of both dyes were removed from the solution in optimal conditions. |
url |
https://doi.org/10.1038/s41598-021-95649-5 |
work_keys_str_mv |
AT siroosshojaei applicationoftaguchimethodandresponsesurfacemethodologyintotheremovalofmalachitegreenandauramineobynaxnanozeolites AT saeedshojaei applicationoftaguchimethodandresponsesurfacemethodologyintotheremovalofmalachitegreenandauramineobynaxnanozeolites AT shahabsband applicationoftaguchimethodandresponsesurfacemethodologyintotheremovalofmalachitegreenandauramineobynaxnanozeolites AT amirabbaskazemzadehfarizhandi applicationoftaguchimethodandresponsesurfacemethodologyintotheremovalofmalachitegreenandauramineobynaxnanozeolites AT miladghoroqi applicationoftaguchimethodandresponsesurfacemethodologyintotheremovalofmalachitegreenandauramineobynaxnanozeolites AT amirmosavi applicationoftaguchimethodandresponsesurfacemethodologyintotheremovalofmalachitegreenandauramineobynaxnanozeolites |
_version_ |
1721215997245915136 |