Crystal structure of {(S)-1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc from synchrotron data
The title ZnII complex, [Zn(NCS)2(C20H21N3)], has been characterized by synchrotron single-crystal diffraction and FT–IR spectroscopy. The central ZnII ion has a distorted square-pyramidal coordination geometry, with three N atoms of the chiral (S) 1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine (S...
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International Union of Crystallography
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doaj-c8cbb1ef326c45f380dd933c490518a32020-11-24T21:28:01ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902017-01-01731171910.1107/S2056989016019253is5466Crystal structure of {(S)-1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc from synchrotron dataDong Won Lee0Jong Won Shin1Daegu-Gyeongbuk Branch, Korea Institute of Science and Technology Information, 90 Yutongdanji-ro, Buk-gu, Daegu 41515, Republic of KoreaDaegu-Gyeongbuk Branch, Korea Institute of Science and Technology Information, 90 Yutongdanji-ro, Buk-gu, Daegu 41515, Republic of KoreaThe title ZnII complex, [Zn(NCS)2(C20H21N3)], has been characterized by synchrotron single-crystal diffraction and FT–IR spectroscopy. The central ZnII ion has a distorted square-pyramidal coordination geometry, with three N atoms of the chiral (S) 1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine (S-ppme) ligand and one N atom of a thiocyanate anion in the equatorial plane, and one N atom of another thiocyanate anion at the apical position. The average Zn—NS-ppme and Zn—NNCS bond lengths are 2.183 (2) and 1.986 (2) Å, respectively. In the crystal, intermolecular C—H...S hydrogen bonds and a face-to-face π–π interaction [centroid–centroid distance = 3.482 (1) Å] link the molecules and give rise to a supramolecular sheet structure parallel to the ac plane.http://scripts.iucr.org/cgi-bin/paper?S2056989016019253crystal structurechiral ligandsodium thiocyanateπ–π interactionssynchrotron data |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Dong Won Lee Jong Won Shin |
spellingShingle |
Dong Won Lee Jong Won Shin Crystal structure of {(S)-1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc from synchrotron data Acta Crystallographica Section E: Crystallographic Communications crystal structure chiral ligand sodium thiocyanate π–π interactions synchrotron data |
author_facet |
Dong Won Lee Jong Won Shin |
author_sort |
Dong Won Lee |
title |
Crystal structure of {(S)-1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc from synchrotron data |
title_short |
Crystal structure of {(S)-1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc from synchrotron data |
title_full |
Crystal structure of {(S)-1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc from synchrotron data |
title_fullStr |
Crystal structure of {(S)-1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc from synchrotron data |
title_full_unstemmed |
Crystal structure of {(S)-1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine-κ3N,N′,N′′}bis(thiocyanato-κN)zinc from synchrotron data |
title_sort |
crystal structure of {(s)-1-phenyl-n,n-bis[(pyridin-2-yl)methyl]ethanamine-κ3n,n′,n′′}bis(thiocyanato-κn)zinc from synchrotron data |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E: Crystallographic Communications |
issn |
2056-9890 |
publishDate |
2017-01-01 |
description |
The title ZnII complex, [Zn(NCS)2(C20H21N3)], has been characterized by synchrotron single-crystal diffraction and FT–IR spectroscopy. The central ZnII ion has a distorted square-pyramidal coordination geometry, with three N atoms of the chiral (S) 1-phenyl-N,N-bis[(pyridin-2-yl)methyl]ethanamine (S-ppme) ligand and one N atom of a thiocyanate anion in the equatorial plane, and one N atom of another thiocyanate anion at the apical position. The average Zn—NS-ppme and Zn—NNCS bond lengths are 2.183 (2) and 1.986 (2) Å, respectively. In the crystal, intermolecular C—H...S hydrogen bonds and a face-to-face π–π interaction [centroid–centroid distance = 3.482 (1) Å] link the molecules and give rise to a supramolecular sheet structure parallel to the ac plane. |
topic |
crystal structure chiral ligand sodium thiocyanate π–π interactions synchrotron data |
url |
http://scripts.iucr.org/cgi-bin/paper?S2056989016019253 |
work_keys_str_mv |
AT dongwonlee crystalstructureofs1phenylnnbispyridin2ylmethylethanaminek3nnnbisthiocyanatoknzincfromsynchrotrondata AT jongwonshin crystalstructureofs1phenylnnbispyridin2ylmethylethanaminek3nnnbisthiocyanatoknzincfromsynchrotrondata |
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1725972053888073728 |