Bis[5-(4-bromophenyl)-4-(tert-butoxycarbonyl)pyrrolidine-2-carboxylato]copper(II) dihydrate
In the title compound, [Cu(C16H19BrNO4)2]·2H2O, the CuII ion resides on an inversion centre and is coordinated by two O and two N atoms from two enantiomeric 5-(4-bromophenyl)-4-(tert-butoxycarbonyl)pyrrolidine-2-carboxylate ligands in a distorted square-planar geometry. The relative st...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811043893 |
| Summary: | In the title compound, [Cu(C16H19BrNO4)2]·2H2O, the CuII ion resides on an inversion centre and is coordinated by two O and two N atoms from two enantiomeric 5-(4-bromophenyl)-4-(tert-butoxycarbonyl)pyrrolidine-2-carboxylate ligands in a distorted square-planar geometry. The relative stereochemistry of the three stereogenic C atoms in each ligand has been determined. In the crystal, intermolecular N—H...O and O—H...O hydrogen bonds link the molecules into layers parallel to the bc plane. The crystal studied was twinned by pseudomerohedry with twin fractions of 0.719 (3) and 0.281 (3). |
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| ISSN: | 1600-5368 |