Synthesis of Propylene-co-Styrenic Monomer Copolymers via Arylation of Chlorinated PP and Their Compatibilization for PP/PS Blend

A series of propylene-co-styrenic monomer copolymers were synthesized using the Friedel–Crafts alkylation reaction between chlorinated PP and substituted benzene, and the effects of these copolymers on a PP/PS (80/20) blend were investigated by using the impact test, morphology observation...

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Main Authors:	Xiangming Fu, Xijun Liu, Chunyu Zhang, Heng Liu, Yanming Hu, Xuequan Zhang
Format:	Article
Language:	English
Published:	MDPI AG 2019-01-01
Series:	Polymers
Subjects:	polypropylene chlorinated polypropylene polystyrene polymer blend compatibilization
Online Access:	http://www.mdpi.com/2073-4360/11/1/157

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spelling	doaj-ca22cb82e7a34472a624cd4679f195922020-11-24T23:13:30ZengMDPI AGPolymers2073-43602019-01-0111115710.3390/polym11010157polym11010157Synthesis of Propylene-co-Styrenic Monomer Copolymers via Arylation of Chlorinated PP and Their Compatibilization for PP/PS BlendXiangming Fu0Xijun Liu1Chunyu Zhang2Heng Liu3Yanming Hu4Xuequan Zhang5College of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, ChinaCollege of Materials Science and Engineering, Qiqihar University, Qiqihar 161006, ChinaCAS Key Laboratory of High-Performance Synthetic Rubber and its Composite Materials, Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, ChinaCAS Key Laboratory of High-Performance Synthetic Rubber and its Composite Materials, Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, ChinaCAS Key Laboratory of High-Performance Synthetic Rubber and its Composite Materials, Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, ChinaCAS Key Laboratory of High-Performance Synthetic Rubber and its Composite Materials, Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, ChinaA series of propylene-co-styrenic monomer copolymers were synthesized using the Friedel–Crafts alkylation reaction between chlorinated PP and substituted benzene, and the effects of these copolymers on a PP/PS (80/20) blend were investigated by using the impact test, morphology observation, thermo- and dynamic mechanical analysis, and rheology measurements. The results showed that the compatibilization efficiency varied as the variation of the substitute on the benzene ring of the styrenic monomer unit was incorporated in the PP chain in an order of methyl > ethyl > methoxyl. The copolymers bearing a crystalline isotactic polypropylene chain sequence and rubbery propylene-co-styrene-like unit chain segments may prepossess imaginable applications, giving an example for the synthesis and applications of PP-based copolymers, initiating a new way to broaden the polyolefin-based material family.http://www.mdpi.com/2073-4360/11/1/157polypropylenechlorinated polypropylenepolystyrenepolymer blendcompatibilization
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Xiangming Fu Xijun Liu Chunyu Zhang Heng Liu Yanming Hu Xuequan Zhang
spellingShingle	Xiangming Fu Xijun Liu Chunyu Zhang Heng Liu Yanming Hu Xuequan Zhang Synthesis of Propylene-co-Styrenic Monomer Copolymers via Arylation of Chlorinated PP and Their Compatibilization for PP/PS Blend Polymers polypropylene chlorinated polypropylene polystyrene polymer blend compatibilization
author_facet	Xiangming Fu Xijun Liu Chunyu Zhang Heng Liu Yanming Hu Xuequan Zhang
author_sort	Xiangming Fu
title	Synthesis of Propylene-co-Styrenic Monomer Copolymers via Arylation of Chlorinated PP and Their Compatibilization for PP/PS Blend
title_short	Synthesis of Propylene-co-Styrenic Monomer Copolymers via Arylation of Chlorinated PP and Their Compatibilization for PP/PS Blend
title_full	Synthesis of Propylene-co-Styrenic Monomer Copolymers via Arylation of Chlorinated PP and Their Compatibilization for PP/PS Blend
title_fullStr	Synthesis of Propylene-co-Styrenic Monomer Copolymers via Arylation of Chlorinated PP and Their Compatibilization for PP/PS Blend
title_full_unstemmed	Synthesis of Propylene-co-Styrenic Monomer Copolymers via Arylation of Chlorinated PP and Their Compatibilization for PP/PS Blend
title_sort	synthesis of propylene-co-styrenic monomer copolymers via arylation of chlorinated pp and their compatibilization for pp/ps blend
publisher	MDPI AG
series	Polymers
issn	2073-4360
publishDate	2019-01-01
description	A series of propylene-co-styrenic monomer copolymers were synthesized using the Friedel–Crafts alkylation reaction between chlorinated PP and substituted benzene, and the effects of these copolymers on a PP/PS (80/20) blend were investigated by using the impact test, morphology observation, thermo- and dynamic mechanical analysis, and rheology measurements. The results showed that the compatibilization efficiency varied as the variation of the substitute on the benzene ring of the styrenic monomer unit was incorporated in the PP chain in an order of methyl > ethyl > methoxyl. The copolymers bearing a crystalline isotactic polypropylene chain sequence and rubbery propylene-co-styrene-like unit chain segments may prepossess imaginable applications, giving an example for the synthesis and applications of PP-based copolymers, initiating a new way to broaden the polyolefin-based material family.
topic	polypropylene chlorinated polypropylene polystyrene polymer blend compatibilization
url	http://www.mdpi.com/2073-4360/11/1/157
work_keys_str_mv	AT xiangmingfu synthesisofpropylenecostyrenicmonomercopolymersviaarylationofchlorinatedppandtheircompatibilizationforpppsblend AT xijunliu synthesisofpropylenecostyrenicmonomercopolymersviaarylationofchlorinatedppandtheircompatibilizationforpppsblend AT chunyuzhang synthesisofpropylenecostyrenicmonomercopolymersviaarylationofchlorinatedppandtheircompatibilizationforpppsblend AT hengliu synthesisofpropylenecostyrenicmonomercopolymersviaarylationofchlorinatedppandtheircompatibilizationforpppsblend AT yanminghu synthesisofpropylenecostyrenicmonomercopolymersviaarylationofchlorinatedppandtheircompatibilizationforpppsblend AT xuequanzhang synthesisofpropylenecostyrenicmonomercopolymersviaarylationofchlorinatedppandtheircompatibilizationforpppsblend
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Synthesis of Propylene-co-Styrenic Monomer Copolymers via Arylation of Chlorinated PP and Their Compatibilization for PP/PS Blend

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