Anodic dissolution of aluminum and anodic passivation in [EMIm]Cl-based ionic liquids
The anodic dissolution of aluminum in Lewis acidic ionic liquids consisting of AlCl3 and 1-ethyl-3-methylimidazolium chloride was studied using linear sweep and cyclic voltammetry, an electrochemical quartz crystal microbalance (EQCM) and chronopotentiometry at ambient temperature. Anodic passivatio...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2020-06-01
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| Series: | Electrochemistry Communications |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S1388248120300710 |
| Summary: | The anodic dissolution of aluminum in Lewis acidic ionic liquids consisting of AlCl3 and 1-ethyl-3-methylimidazolium chloride was studied using linear sweep and cyclic voltammetry, an electrochemical quartz crystal microbalance (EQCM) and chronopotentiometry at ambient temperature. Anodic passivation of the working electrode was observed in a 2:1 electrolyte while no passivation was found in a 1.5:1 electrolyte. Chronopotentiometry proves the passivation to be caused by local solidification of the electrolyte due to an increase in the aluminum concentration near the anode. EQCM data support these results. |
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| ISSN: | 1388-2481 |