Bis(μ-2′-carboxylatobiphenyl-2-carboxylic acid-κ2O2:O2′)bis[(2,2′-bipyridine-κ2N,N′)(2′-carboxylatobiphenyl-2-carboxylic acid-κO2′)zinc(II)]
In the dimeric title compound, [Zn2(C14H9O4)4(C10H8N2)2], the ZnII ions are pentacoordinated by one 2,2′-bipyridyl ligand and by three O atoms from three 2′-carboxylatobiphenyl-2-carboxylic acid ligands. Two of the 2′-carboxylatobiphenyl-2-carboxylic acid li...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809045541 |
| Summary: | In the dimeric title compound, [Zn2(C14H9O4)4(C10H8N2)2], the ZnII ions are pentacoordinated by one 2,2′-bipyridyl ligand and by three O atoms from three 2′-carboxylatobiphenyl-2-carboxylic acid ligands. Two of the 2′-carboxylatobiphenyl-2-carboxylic acid ligands act as bridging ligands and, together with two zinc(II) cations, produce an 18-membered ring system. The remaining 2′-carboxylatobiphenyl-2-carboxylic acid ligands work as monodentate ligands. The crystal packing diagram is consolidated by O—H...O hydrogen bonds. |
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| ISSN: | 1600-5368 |