Poly[diaquabis(μ-4,4′-bipyridine-κ2N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ2O:O′)dicobalt(II)]
In the title compound, [Co2(SO4)2(C10H8N2)2(C2H6O2)2(H2O)2]n, there are two crystallographically independent CoII ions, each of which lies on a twofold rotation axis and has a slightly distorted octahedral environment. One CoII ion is coordinated by two N atoms from two bridging 4,4′-bipyr...
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International Union of Crystallography
2013-04-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813006685 |
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doaj-cbb8e8eee0964dc8bd6e0913e03ad6942020-11-24T21:32:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-04-01694m207m20810.1107/S1600536813006685Poly[diaquabis(μ-4,4′-bipyridine-κ2N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ2O:O′)dicobalt(II)]Kai-Long ZhongIn the title compound, [Co2(SO4)2(C10H8N2)2(C2H6O2)2(H2O)2]n, there are two crystallographically independent CoII ions, each of which lies on a twofold rotation axis and has a slightly distorted octahedral environment. One CoII ion is coordinated by two N atoms from two bridging 4,4′-bipyridine (4,4′-bipy) ligands, two O atoms from two sulfate ions and two O atoms from aqua ligands. The second CoII ion is similar but with ethane-1,2-diol ligands in place of water molecules. The sulfate anions act as bridging ligands to link two adjacent CoII ions together, leading to the formation of linear ...Co1Co2Co1Co2...chains along the a axis. Adjacent chains are further bridged by 4,4′-bipy ligands, which are also located on the twofold rotation axis, resulting in a two-dimensional layered polymer extending parallel to (001). In the crystal, the layers are linked by extensive O—H...O hydrogen-bonding interactions involving the O atoms of the water molecules and ethane-1,2-diol molecules, resulting in a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536813006685 |
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DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Kai-Long Zhong |
spellingShingle |
Kai-Long Zhong Poly[diaquabis(μ-4,4′-bipyridine-κ2N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ2O:O′)dicobalt(II)] Acta Crystallographica Section E |
author_facet |
Kai-Long Zhong |
author_sort |
Kai-Long Zhong |
title |
Poly[diaquabis(μ-4,4′-bipyridine-κ2N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ2O:O′)dicobalt(II)] |
title_short |
Poly[diaquabis(μ-4,4′-bipyridine-κ2N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ2O:O′)dicobalt(II)] |
title_full |
Poly[diaquabis(μ-4,4′-bipyridine-κ2N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ2O:O′)dicobalt(II)] |
title_fullStr |
Poly[diaquabis(μ-4,4′-bipyridine-κ2N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ2O:O′)dicobalt(II)] |
title_full_unstemmed |
Poly[diaquabis(μ-4,4′-bipyridine-κ2N:N′)bis(ethane-1,2-diol-κO)bis(μ-sulfato-κ2O:O′)dicobalt(II)] |
title_sort |
poly[diaquabis(μ-4,4′-bipyridine-κ2n:n′)bis(ethane-1,2-diol-κo)bis(μ-sulfato-κ2o:o′)dicobalt(ii)] |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2013-04-01 |
description |
In the title compound, [Co2(SO4)2(C10H8N2)2(C2H6O2)2(H2O)2]n, there are two crystallographically independent CoII ions, each of which lies on a twofold rotation axis and has a slightly distorted octahedral environment. One CoII ion is coordinated by two N atoms from two bridging 4,4′-bipyridine (4,4′-bipy) ligands, two O atoms from two sulfate ions and two O atoms from aqua ligands. The second CoII ion is similar but with ethane-1,2-diol ligands in place of water molecules. The sulfate anions act as bridging ligands to link two adjacent CoII ions together, leading to the formation of linear ...Co1Co2Co1Co2...chains along the a axis. Adjacent chains are further bridged by 4,4′-bipy ligands, which are also located on the twofold rotation axis, resulting in a two-dimensional layered polymer extending parallel to (001). In the crystal, the layers are linked by extensive O—H...O hydrogen-bonding interactions involving the O atoms of the water molecules and ethane-1,2-diol molecules, resulting in a three-dimensional supramolecular network. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536813006685 |
work_keys_str_mv |
AT kailongzhong polydiaquabis956448242bipyridine9542nn8242bisethane12diol954obis956sulfato9542oo8242dicobaltii |
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1725958002261884928 |