4,4′-Diazenediyldipyridinium (4-pyridyldiazenyl)pyridinium octacyanidomolybdate(V) tetrahydrate

4,4′-Diazenediyldipyridinium (4-pyridyldiazenyl)pyridinium octacyanidomolybdate(V) tetrahydrate

The structure of the title complex, (C10H10N4)(C10H9N4)[Mo(CN)8]·4H2O, consists of 4,4′-diazenediyldipyridinium and (4-pyridyldiazenyl)pyridinium cations disordered over the same site, an [Mo(CN)8]3− anion and four uncoordinated water molecules. The cations (crystallogra...

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Main Authors: Ai-Hua Yuan, Hu Zhou, Wen-Yan Liu
Format: Article
Language:English
Published: International Union of Crystallography 2008-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680802494X
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spelling doaj-cc2c4f0184ad45a88105258752a55ba42020-11-25T00:12:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-09-01649m1151m115110.1107/S160053680802494X4,4′-Diazenediyldipyridinium (4-pyridyldiazenyl)pyridinium octacyanidomolybdate(V) tetrahydrateAi-Hua YuanHu ZhouWen-Yan LiuThe structure of the title complex, (C10H10N4)(C10H9N4)[Mo(CN)8]·4H2O, consists of 4,4′-diazenediyldipyridinium and (4-pyridyldiazenyl)pyridinium cations disordered over the same site, an [Mo(CN)8]3− anion and four uncoordinated water molecules. The cations (crystallographic symmetry, 2) and the [Mo(CN)8]3− anion (crystallographic symmetry, 222) are arranged in an alternating fashion, forming a two-dimensional layered structure through hydrogen bonds. Hydrogen bonds, π–π stacking interactions (shortest distance = 4.7872 Å) and van der Waals forces between adjacent layers generate a three-dimensional supramolecular structure.http://scripts.iucr.org/cgi-bin/paper?S160053680802494X
collection DOAJ
language English
format Article
sources DOAJ
author Ai-Hua Yuan
Hu Zhou
Wen-Yan Liu
spellingShingle Ai-Hua Yuan
Hu Zhou
Wen-Yan Liu
4,4′-Diazenediyldipyridinium (4-pyridyldiazenyl)pyridinium octacyanidomolybdate(V) tetrahydrate
Acta Crystallographica Section E
author_facet Ai-Hua Yuan
Hu Zhou
Wen-Yan Liu
author_sort Ai-Hua Yuan
title 4,4′-Diazenediyldipyridinium (4-pyridyldiazenyl)pyridinium octacyanidomolybdate(V) tetrahydrate
title_short 4,4′-Diazenediyldipyridinium (4-pyridyldiazenyl)pyridinium octacyanidomolybdate(V) tetrahydrate
title_full 4,4′-Diazenediyldipyridinium (4-pyridyldiazenyl)pyridinium octacyanidomolybdate(V) tetrahydrate
title_fullStr 4,4′-Diazenediyldipyridinium (4-pyridyldiazenyl)pyridinium octacyanidomolybdate(V) tetrahydrate
title_full_unstemmed 4,4′-Diazenediyldipyridinium (4-pyridyldiazenyl)pyridinium octacyanidomolybdate(V) tetrahydrate
title_sort 4,4′-diazenediyldipyridinium (4-pyridyldiazenyl)pyridinium octacyanidomolybdate(v) tetrahydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-09-01
description The structure of the title complex, (C10H10N4)(C10H9N4)[Mo(CN)8]·4H2O, consists of 4,4′-diazenediyldipyridinium and (4-pyridyldiazenyl)pyridinium cations disordered over the same site, an [Mo(CN)8]3− anion and four uncoordinated water molecules. The cations (crystallographic symmetry, 2) and the [Mo(CN)8]3− anion (crystallographic symmetry, 222) are arranged in an alternating fashion, forming a two-dimensional layered structure through hydrogen bonds. Hydrogen bonds, π–π stacking interactions (shortest distance = 4.7872 Å) and van der Waals forces between adjacent layers generate a three-dimensional supramolecular structure.
url http://scripts.iucr.org/cgi-bin/paper?S160053680802494X
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AT huzhou 448242diazenediyldipyridinium4pyridyldiazenylpyridiniumoctacyanidomolybdatevtetrahydrate
AT wenyanliu 448242diazenediyldipyridinium4pyridyldiazenylpyridiniumoctacyanidomolybdatevtetrahydrate
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