Electrochemical Performance Improvement of the Catalyst of the Methanol Microfuel Cell Using Carbon Nanotubes
In this research, the electrocatalytic activity of platinum-ruthenium nanoparticles on carbon nanotubes and carbon black in methanol oxidation reaction has been investigated. Moreover, the electrochemical performance of a single passive direct methanol fuel cell run by these two different electrocat...
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Series: | International Journal of Chemical Engineering |
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doaj-cd09ac50d35248cca81403f585211dec2021-07-02T21:09:02ZengHindawi LimitedInternational Journal of Chemical Engineering1687-80782021-01-01202110.1155/2021/8894768Electrochemical Performance Improvement of the Catalyst of the Methanol Microfuel Cell Using Carbon NanotubesMohammad Kazemi Nasrabadi0Amir Ebrahimi-Moghadam1Ravinder Kumar2Narjes Nabipour3Aerospace Engineering DepartmentFaculty of Mechanical EngineeringDepartment of Mechanical EngineeringInstitute of Research and DevelopmentIn this research, the electrocatalytic activity of platinum-ruthenium nanoparticles on carbon nanotubes and carbon black in methanol oxidation reaction has been investigated. Moreover, the electrochemical performance of a single passive direct methanol fuel cell run by these two different electrocatalysts has been reported. Physical characterization and electrochemical tests reveal the superiority of PtRu on carbon nanotubes. Based on the voltammetry outcomes, it was found that methanol oxidation reaction kinetics has been improved on the nanotube-supported catalyst. The current density of oxidation reaction has increased up to 62% in nanotube sample compared to carbon black-supported one. The electrochemical test results have shown that the carbon nanotubes increase the performance of the microfuel cell by 37% at maximum power density, compared to the carbon black. Moreover, the resistance of the samples supported by carbon nanotubes to poisonous intermediate species has been found 3% more than carbon black-supported one. According to the chronoamperometry test results, it was concluded that the performance and sustainability of the carbon nanotube electrocatalyst show a remarkable improvement compared to carbon black electrocatalyst in the long term.http://dx.doi.org/10.1155/2021/8894768 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Mohammad Kazemi Nasrabadi Amir Ebrahimi-Moghadam Ravinder Kumar Narjes Nabipour |
spellingShingle |
Mohammad Kazemi Nasrabadi Amir Ebrahimi-Moghadam Ravinder Kumar Narjes Nabipour Electrochemical Performance Improvement of the Catalyst of the Methanol Microfuel Cell Using Carbon Nanotubes International Journal of Chemical Engineering |
author_facet |
Mohammad Kazemi Nasrabadi Amir Ebrahimi-Moghadam Ravinder Kumar Narjes Nabipour |
author_sort |
Mohammad Kazemi Nasrabadi |
title |
Electrochemical Performance Improvement of the Catalyst of the Methanol Microfuel Cell Using Carbon Nanotubes |
title_short |
Electrochemical Performance Improvement of the Catalyst of the Methanol Microfuel Cell Using Carbon Nanotubes |
title_full |
Electrochemical Performance Improvement of the Catalyst of the Methanol Microfuel Cell Using Carbon Nanotubes |
title_fullStr |
Electrochemical Performance Improvement of the Catalyst of the Methanol Microfuel Cell Using Carbon Nanotubes |
title_full_unstemmed |
Electrochemical Performance Improvement of the Catalyst of the Methanol Microfuel Cell Using Carbon Nanotubes |
title_sort |
electrochemical performance improvement of the catalyst of the methanol microfuel cell using carbon nanotubes |
publisher |
Hindawi Limited |
series |
International Journal of Chemical Engineering |
issn |
1687-8078 |
publishDate |
2021-01-01 |
description |
In this research, the electrocatalytic activity of platinum-ruthenium nanoparticles on carbon nanotubes and carbon black in methanol oxidation reaction has been investigated. Moreover, the electrochemical performance of a single passive direct methanol fuel cell run by these two different electrocatalysts has been reported. Physical characterization and electrochemical tests reveal the superiority of PtRu on carbon nanotubes. Based on the voltammetry outcomes, it was found that methanol oxidation reaction kinetics has been improved on the nanotube-supported catalyst. The current density of oxidation reaction has increased up to 62% in nanotube sample compared to carbon black-supported one. The electrochemical test results have shown that the carbon nanotubes increase the performance of the microfuel cell by 37% at maximum power density, compared to the carbon black. Moreover, the resistance of the samples supported by carbon nanotubes to poisonous intermediate species has been found 3% more than carbon black-supported one. According to the chronoamperometry test results, it was concluded that the performance and sustainability of the carbon nanotube electrocatalyst show a remarkable improvement compared to carbon black electrocatalyst in the long term. |
url |
http://dx.doi.org/10.1155/2021/8894768 |
work_keys_str_mv |
AT mohammadkazeminasrabadi electrochemicalperformanceimprovementofthecatalystofthemethanolmicrofuelcellusingcarbonnanotubes AT amirebrahimimoghadam electrochemicalperformanceimprovementofthecatalystofthemethanolmicrofuelcellusingcarbonnanotubes AT ravinderkumar electrochemicalperformanceimprovementofthecatalystofthemethanolmicrofuelcellusingcarbonnanotubes AT narjesnabipour electrochemicalperformanceimprovementofthecatalystofthemethanolmicrofuelcellusingcarbonnanotubes |
_version_ |
1721322425489031168 |