(E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate

(E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate

The title compound, C12H18N82+·2NO3−·2H2O, was synthesized unexpectedly from 3-amino-1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium chloride and cerium(IV) ammonium nitrate. The cation has a crystallographically imposed centre of symmetry. In the cryst...

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Main Authors: Jin-Mei Chen, Hong Zhao
Format: Article
Language:English
Published: International Union of Crystallography 2012-01-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811053347
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spelling doaj-cd2960f0d0694953bb71c914d1898c132020-11-25T00:57:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681o151o15110.1107/S1600536811053347(E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrateJin-Mei ChenHong ZhaoThe title compound, C12H18N82+·2NO3−·2H2O, was synthesized unexpectedly from 3-amino-1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium chloride and cerium(IV) ammonium nitrate. The cation has a crystallographically imposed centre of symmetry. In the crystal, the ions and water molecules are linked via O—H...N, N—H...O and O—H...O hydrogen bonds into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536811053347
collection DOAJ
language English
format Article
sources DOAJ
author Jin-Mei Chen
Hong Zhao
spellingShingle Jin-Mei Chen
Hong Zhao
(E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate
Acta Crystallographica Section E
author_facet Jin-Mei Chen
Hong Zhao
author_sort Jin-Mei Chen
title (E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate
title_short (E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate
title_full (E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate
title_fullStr (E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate
title_full_unstemmed (E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate
title_sort (e)-3,3′-(diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2012-01-01
description The title compound, C12H18N82+·2NO3−·2H2O, was synthesized unexpectedly from 3-amino-1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium chloride and cerium(IV) ammonium nitrate. The cation has a crystallographically imposed centre of symmetry. In the crystal, the ions and water molecules are linked via O—H...N, N—H...O and O—H...O hydrogen bonds into a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811053347
work_keys_str_mv AT jinmeichen e33amp8242diazene12diylbis1methyl1456tetrahydropyrrolo34cpyrazol5iumdinitratedihydrate
AT hongzhao e33amp8242diazene12diylbis1methyl1456tetrahydropyrrolo34cpyrazol5iumdinitratedihydrate
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