(E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate
The title compound, C12H18N82+·2NO3−·2H2O, was synthesized unexpectedly from 3-amino-1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium chloride and cerium(IV) ammonium nitrate. The cation has a crystallographically imposed centre of symmetry. In the cryst...
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International Union of Crystallography
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811053347 |
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doaj-cd2960f0d0694953bb71c914d1898c132020-11-25T00:57:59ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-01-01681o151o15110.1107/S1600536811053347(E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrateJin-Mei ChenHong ZhaoThe title compound, C12H18N82+·2NO3−·2H2O, was synthesized unexpectedly from 3-amino-1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium chloride and cerium(IV) ammonium nitrate. The cation has a crystallographically imposed centre of symmetry. In the crystal, the ions and water molecules are linked via O—H...N, N—H...O and O—H...O hydrogen bonds into a three-dimensional network.http://scripts.iucr.org/cgi-bin/paper?S1600536811053347 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Jin-Mei Chen Hong Zhao |
spellingShingle |
Jin-Mei Chen Hong Zhao (E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate Acta Crystallographica Section E |
author_facet |
Jin-Mei Chen Hong Zhao |
author_sort |
Jin-Mei Chen |
title |
(E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate |
title_short |
(E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate |
title_full |
(E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate |
title_fullStr |
(E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate |
title_full_unstemmed |
(E)-3,3′-(Diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate |
title_sort |
(e)-3,3′-(diazene-1,2-diyl)bis(1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium) dinitrate dihydrate |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2012-01-01 |
description |
The title compound, C12H18N82+·2NO3−·2H2O, was synthesized unexpectedly from 3-amino-1-methyl-1,4,5,6-tetrahydropyrrolo[3,4-c]pyrazol-5-ium chloride and cerium(IV) ammonium nitrate. The cation has a crystallographically imposed centre of symmetry. In the crystal, the ions and water molecules are linked via O—H...N, N—H...O and O—H...O hydrogen bonds into a three-dimensional network. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811053347 |
work_keys_str_mv |
AT jinmeichen e33amp8242diazene12diylbis1methyl1456tetrahydropyrrolo34cpyrazol5iumdinitratedihydrate AT hongzhao e33amp8242diazene12diylbis1methyl1456tetrahydropyrrolo34cpyrazol5iumdinitratedihydrate |
_version_ |
1725221830059360256 |