Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)

Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)

The title compound, (C5H14N2)[CuCl4], was synthesized by hydrothermal reaction of CuCl2 with 1-methylpiperazine in an HCl/water solution. Both amine N atoms are protonated. The piperazine ring adopts a chair conformation. The Cu—Cl distances in the tetrahedral anion are in the range 2....

Full description

Bibliographic Details
Main Author: Cong-hu Peng
Format: Article
Language:English
Published: International Union of Crystallography 2011-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811024354
id doaj-cd5631a0b53245a9bba060c19448a3e0
record_format Article
spelling doaj-cd5631a0b53245a9bba060c19448a3e02020-11-25T01:13:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-07-01677m979m97910.1107/S1600536811024354Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)Cong-hu PengThe title compound, (C5H14N2)[CuCl4], was synthesized by hydrothermal reaction of CuCl2 with 1-methylpiperazine in an HCl/water solution. Both amine N atoms are protonated. The piperazine ring adopts a chair conformation. The Cu—Cl distances in the tetrahedral anion are in the range 2.2360 (7)–2.2732 (7) Å. In the crystal, moderately strong and weak intermolecular N—H...Cl hydrogen bonds link the anion and cation units into an infinite two-dimensional network parallel to the ab plane.http://scripts.iucr.org/cgi-bin/paper?S1600536811024354
collection DOAJ
language English
format Article
sources DOAJ
author Cong-hu Peng
spellingShingle Cong-hu Peng
Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)
Acta Crystallographica Section E
author_facet Cong-hu Peng
author_sort Cong-hu Peng
title Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)
title_short Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)
title_full Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)
title_fullStr Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)
title_full_unstemmed Bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(II)
title_sort bis(1-methylpiperazine-1,4-diium) tetrachloridocuprate(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2011-07-01
description The title compound, (C5H14N2)[CuCl4], was synthesized by hydrothermal reaction of CuCl2 with 1-methylpiperazine in an HCl/water solution. Both amine N atoms are protonated. The piperazine ring adopts a chair conformation. The Cu—Cl distances in the tetrahedral anion are in the range 2.2360 (7)–2.2732 (7) Å. In the crystal, moderately strong and weak intermolecular N—H...Cl hydrogen bonds link the anion and cation units into an infinite two-dimensional network parallel to the ab plane.
url http://scripts.iucr.org/cgi-bin/paper?S1600536811024354
work_keys_str_mv AT conghupeng bis1methylpiperazine14diiumtetrachloridocuprateii
_version_ 1725162738455412736

Similar Items