Open questions in boron species with globally 4n π systems

The Hückel rule defines that monocyclic and planar conjugated systems containing [4n + 2] π electrons are aromatic. Here, the authors highlight boron species that feature a globally 4n π system, defying the Hückel rule, but nonetheless exhibit aromaticity.

Bibliographic Details
Main Authors: Kei Ota, Rei Kinjo
Format: Article
Language:English
Published: Nature Publishing Group 2021-07-01
Series:Communications Chemistry
Online Access:https://doi.org/10.1038/s42004-021-00542-x
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spelling doaj-cd6a294662b342ee858f3106ce23817d2021-07-18T11:05:55ZengNature Publishing GroupCommunications Chemistry2399-36692021-07-01411310.1038/s42004-021-00542-xOpen questions in boron species with globally 4n π systemsKei Ota0Rei Kinjo1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological UniversityDivision of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological UniversityThe Hückel rule defines that monocyclic and planar conjugated systems containing [4n + 2] π electrons are aromatic. Here, the authors highlight boron species that feature a globally 4n π system, defying the Hückel rule, but nonetheless exhibit aromaticity.https://doi.org/10.1038/s42004-021-00542-x
collection DOAJ
language English
format Article
sources DOAJ
author Kei Ota
Rei Kinjo
spellingShingle Kei Ota
Rei Kinjo
Open questions in boron species with globally 4n π systems
Communications Chemistry
author_facet Kei Ota
Rei Kinjo
author_sort Kei Ota
title Open questions in boron species with globally 4n π systems
title_short Open questions in boron species with globally 4n π systems
title_full Open questions in boron species with globally 4n π systems
title_fullStr Open questions in boron species with globally 4n π systems
title_full_unstemmed Open questions in boron species with globally 4n π systems
title_sort open questions in boron species with globally 4n π systems
publisher Nature Publishing Group
series Communications Chemistry
issn 2399-3669
publishDate 2021-07-01
description The Hückel rule defines that monocyclic and planar conjugated systems containing [4n + 2] π electrons are aromatic. Here, the authors highlight boron species that feature a globally 4n π system, defying the Hückel rule, but nonetheless exhibit aromaticity.
url https://doi.org/10.1038/s42004-021-00542-x
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AT reikinjo openquestionsinboronspecieswithglobally4npsystems
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