{2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(II)

{2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(II)

In the title mononuclear nickel(II) complex, [Ni(C12H17N2O2)(NCS)], the metal atom is four-coordinated in a tetrahedrally distorted square-planar geometry by the phenolate O atom, the imine N atom and the amine N atom of the Schiff base ligand and by the N atom of a thiocyanate ligand. In the crysta...

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Main Author: Lin Liu
Format: Article
Language:English
Published: International Union of Crystallography 2010-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536810002357
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spelling doaj-cd88687211744e3dbb66a3f81713df862020-11-25T00:49:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m195m19510.1107/S1600536810002357{2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(II)Lin LiuIn the title mononuclear nickel(II) complex, [Ni(C12H17N2O2)(NCS)], the metal atom is four-coordinated in a tetrahedrally distorted square-planar geometry by the phenolate O atom, the imine N atom and the amine N atom of the Schiff base ligand and by the N atom of a thiocyanate ligand. In the crystal structure, centrosymmetrically related molecules are linked into dimers through intermolecular N—H...O hydrogen bonds. These dimers are further connected by intermolecular C—H...S hydrogen bonds, forming chains running parallel to [101]. http://scripts.iucr.org/cgi-bin/paper?S1600536810002357
collection DOAJ
language English
format Article
sources DOAJ
author Lin Liu
spellingShingle Lin Liu
{2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(II)
Acta Crystallographica Section E
author_facet Lin Liu
author_sort Lin Liu
title {2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(II)
title_short {2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(II)
title_full {2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(II)
title_fullStr {2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(II)
title_full_unstemmed {2-[2-(Ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(II)
title_sort {2-[2-(ethylamino)ethyliminomethyl]-5-methoxyphenolato}thiocyanatonickel(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-02-01
description In the title mononuclear nickel(II) complex, [Ni(C12H17N2O2)(NCS)], the metal atom is four-coordinated in a tetrahedrally distorted square-planar geometry by the phenolate O atom, the imine N atom and the amine N atom of the Schiff base ligand and by the N atom of a thiocyanate ligand. In the crystal structure, centrosymmetrically related molecules are linked into dimers through intermolecular N—H...O hydrogen bonds. These dimers are further connected by intermolecular C—H...S hydrogen bonds, forming chains running parallel to [101].
url http://scripts.iucr.org/cgi-bin/paper?S1600536810002357
work_keys_str_mv AT linliu 22ethylaminoethyliminomethyl5methoxyphenolatothiocyanatonickelii
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