A one-dimensional zigzag coordination polymer: catena-poly[[[triaquacadmium(II)]-[μ-2,2′-(5-methyl-1,3-phenylenedioxy)diacetato-κ4O,O′:O′′,O′′′]] monohydrate]
In the title one-dimensional coordination polymer, {[Cd(C11H10O6)(H2O)3]·H2O}n, the 2,2′-(5-methyl-1,3-phenylenedioxy)diacetate dianions connect CdII ions in a head-to-tail fashion to generate zigzag chains. The coordination geometry of the Cd atom is distorted pentagonal bipyrami...
Main Authors: | , , , |
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Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2008-02-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807068031 |
Summary: | In the title one-dimensional coordination polymer, {[Cd(C11H10O6)(H2O)3]·H2O}n, the 2,2′-(5-methyl-1,3-phenylenedioxy)diacetate dianions connect CdII ions in a head-to-tail fashion to generate zigzag chains. The coordination geometry of the Cd atom is distorted pentagonal bipyramidal. There are O—H...O hydrogen bonds between the carboxyl O atoms, the aqua ligands and the uncoordinated water molecules. |
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ISSN: | 1600-5368 |