Monosegemented flow potentiometric titration for the determination of chloride in milk and wine
An automated flow potentiometric titration procedure for the determination of chloride in milk and wine exploiting the monosegmented flow approach is described. The flow network was designed based on a six-way solenoid valve, controlled by a microcomputer running software written in VisualBasic 3.0,...
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2003-01-01
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doaj-ceb8ec9a940b4870b4a05fbae91fde902020-11-24T23:41:37ZengSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society0103-50532003-01-01142259264Monosegemented flow potentiometric titration for the determination of chloride in milk and wineVieira Jonas A.Raimundo Jr. Ivo M.Reis Boaventura F.Montenegro M. Conceição B.S.M.Araújo Alberto N.An automated flow potentiometric titration procedure for the determination of chloride in milk and wine exploiting the monosegmented flow approach is described. The flow network was designed based on a six-way solenoid valve, controlled by a microcomputer running software written in VisualBasic 3.0, allowing selection of the titration conditions. An Ag2S tubular electrode selective for Cl- and a conventional Ag/AgCl electrode were employed as indicator and reference, respectively. An algorithm based on the potential difference between two subsequent titrant additions was developed, allowing to reach the end point in less than 10 attempts, with a precision better than 1.0%. The proposed system was evaluated by determining chloride in milk and wine, using a standard AgNO3 solution as titrant. Accuracy was ascertained by comparing the results with those obtained using the AOAC procedure. No significant difference at a 95% confidence level was observed.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000200012potentiometric titrationmonossegmented flowmulticommutationion selective electrodechloride in milkchloride in wine |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Vieira Jonas A. Raimundo Jr. Ivo M. Reis Boaventura F. Montenegro M. Conceição B.S.M. Araújo Alberto N. |
spellingShingle |
Vieira Jonas A. Raimundo Jr. Ivo M. Reis Boaventura F. Montenegro M. Conceição B.S.M. Araújo Alberto N. Monosegemented flow potentiometric titration for the determination of chloride in milk and wine Journal of the Brazilian Chemical Society potentiometric titration monossegmented flow multicommutation ion selective electrode chloride in milk chloride in wine |
author_facet |
Vieira Jonas A. Raimundo Jr. Ivo M. Reis Boaventura F. Montenegro M. Conceição B.S.M. Araújo Alberto N. |
author_sort |
Vieira Jonas A. |
title |
Monosegemented flow potentiometric titration for the determination of chloride in milk and wine |
title_short |
Monosegemented flow potentiometric titration for the determination of chloride in milk and wine |
title_full |
Monosegemented flow potentiometric titration for the determination of chloride in milk and wine |
title_fullStr |
Monosegemented flow potentiometric titration for the determination of chloride in milk and wine |
title_full_unstemmed |
Monosegemented flow potentiometric titration for the determination of chloride in milk and wine |
title_sort |
monosegemented flow potentiometric titration for the determination of chloride in milk and wine |
publisher |
Sociedade Brasileira de Química |
series |
Journal of the Brazilian Chemical Society |
issn |
0103-5053 |
publishDate |
2003-01-01 |
description |
An automated flow potentiometric titration procedure for the determination of chloride in milk and wine exploiting the monosegmented flow approach is described. The flow network was designed based on a six-way solenoid valve, controlled by a microcomputer running software written in VisualBasic 3.0, allowing selection of the titration conditions. An Ag2S tubular electrode selective for Cl- and a conventional Ag/AgCl electrode were employed as indicator and reference, respectively. An algorithm based on the potential difference between two subsequent titrant additions was developed, allowing to reach the end point in less than 10 attempts, with a precision better than 1.0%. The proposed system was evaluated by determining chloride in milk and wine, using a standard AgNO3 solution as titrant. Accuracy was ascertained by comparing the results with those obtained using the AOAC procedure. No significant difference at a 95% confidence level was observed. |
topic |
potentiometric titration monossegmented flow multicommutation ion selective electrode chloride in milk chloride in wine |
url |
http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000200012 |
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