Encapsulation of Dirhenium(III) Carboxylates into Zirconium Phosphate
Present work reports the synthesis of zirconium phosphate nanoparticles containing dirhenium(III) substance bis-dimethylsulfoxide-cis-tetrachlorodi-μ-pivalatodirhenium(III) with formula cis-Re2(C(CH3)3COO)2Cl4∙2DMSO (I) and q-zirconium phosphate with formula q-Zr(HPO4)2∙6H2O (ZrP). The intercalation...
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Slovenian Chemical Society
2020-06-01
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doaj-cedb7b676aa74532804cb804382944d82020-11-25T03:47:06ZengSlovenian Chemical SocietyActa Chimica Slovenica1318-02071580-31552020-06-0167248749510.17344/acsi.2019.5505823Encapsulation of Dirhenium(III) Carboxylates into Zirconium PhosphateAnastasiia Slіpkan0Nataliia Shtemenko1Dina Kytova2Alexander Shtemenko3Ukrainian State University of Chemical TechnologyDnipro University of TechnologyUkrainian State University of Chemical TechnologyUkrainian State University of Chemical TechnologyPresent work reports the synthesis of zirconium phosphate nanoparticles containing dirhenium(III) substance bis-dimethylsulfoxide-cis-tetrachlorodi-μ-pivalatodirhenium(III) with formula cis-Re2(C(CH3)3COO)2Cl4∙2DMSO (I) and q-zirconium phosphate with formula q-Zr(HPO4)2∙6H2O (ZrP). The intercalation process was monitored by EAS. Due to the spectral characteristics of the quadruple bond the conclusion was made that the obtained intercalated compounds had cis-configuration of ligands around cluster dirhenium fragment. The proposed mechanism of intercalation includes the substitution of the axial ligands of I by phosphate groups of ZrP first on the surface of ZrP, than in the inner layers. Two received products of the intercalation were characterized by SEM, XRPD, FT-IR, TGA analysis witnessing about successful intercalation process. The formation of new phases with interlayer distances of 10.53 – 16.6 Å was found, the average size of obtained platelets was 100-200 nm.https://journals.matheo.si/index.php/ACSi/article/view/5505dirhenium(iii) carboxylateszirconium phosphatenanoparticlesintercalation |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Anastasiia Slіpkan Nataliia Shtemenko Dina Kytova Alexander Shtemenko |
spellingShingle |
Anastasiia Slіpkan Nataliia Shtemenko Dina Kytova Alexander Shtemenko Encapsulation of Dirhenium(III) Carboxylates into Zirconium Phosphate Acta Chimica Slovenica dirhenium(iii) carboxylates zirconium phosphate nanoparticles intercalation |
author_facet |
Anastasiia Slіpkan Nataliia Shtemenko Dina Kytova Alexander Shtemenko |
author_sort |
Anastasiia Slіpkan |
title |
Encapsulation of Dirhenium(III) Carboxylates into Zirconium Phosphate |
title_short |
Encapsulation of Dirhenium(III) Carboxylates into Zirconium Phosphate |
title_full |
Encapsulation of Dirhenium(III) Carboxylates into Zirconium Phosphate |
title_fullStr |
Encapsulation of Dirhenium(III) Carboxylates into Zirconium Phosphate |
title_full_unstemmed |
Encapsulation of Dirhenium(III) Carboxylates into Zirconium Phosphate |
title_sort |
encapsulation of dirhenium(iii) carboxylates into zirconium phosphate |
publisher |
Slovenian Chemical Society |
series |
Acta Chimica Slovenica |
issn |
1318-0207 1580-3155 |
publishDate |
2020-06-01 |
description |
Present work reports the synthesis of zirconium phosphate nanoparticles containing dirhenium(III) substance bis-dimethylsulfoxide-cis-tetrachlorodi-μ-pivalatodirhenium(III) with formula cis-Re2(C(CH3)3COO)2Cl4∙2DMSO (I) and q-zirconium phosphate with formula q-Zr(HPO4)2∙6H2O (ZrP). The intercalation process was monitored by EAS. Due to the spectral characteristics of the quadruple bond the conclusion was made that the obtained intercalated compounds had cis-configuration of ligands around cluster dirhenium fragment. The proposed mechanism of intercalation includes the substitution of the axial ligands of I by phosphate groups of ZrP first on the surface of ZrP, than in the inner layers. Two received products of the intercalation were characterized by SEM, XRPD, FT-IR, TGA analysis witnessing about successful intercalation process. The formation of new phases with interlayer distances of 10.53 – 16.6 Å was found, the average size of obtained platelets was 100-200 nm. |
topic |
dirhenium(iii) carboxylates zirconium phosphate nanoparticles intercalation |
url |
https://journals.matheo.si/index.php/ACSi/article/view/5505 |
work_keys_str_mv |
AT anastasiiaslípkan encapsulationofdirheniumiiicarboxylatesintozirconiumphosphate AT nataliiashtemenko encapsulationofdirheniumiiicarboxylatesintozirconiumphosphate AT dinakytova encapsulationofdirheniumiiicarboxylatesintozirconiumphosphate AT alexandershtemenko encapsulationofdirheniumiiicarboxylatesintozirconiumphosphate |
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1724503509348384768 |