cis-Aquachloridobis(1,10-phenanthroline-κ2N,N′)cobalt(II) chloride 2.5-hydrate

cis-Aquachloridobis(1,10-phenanthroline-κ2N,N′)cobalt(II) chloride 2.5-hydrate

In the title complex, [CoCl(C12H8N2)2(H2O)]Cl·2.5H2O, the CoII ion is coordinated by four N atoms of two bis-chelating 1,10-phenanthroline (phen) ligands, one water molecule and a chloride ligand in a distorted octahedral environment. The dihedral angle between the two phen ligands is 8...

Full description

Bibliographic Details
Main Authors: K. Arun Kumar, A. Dayalan, K. SethuSankar
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809038422
id doaj-cf2b3ef699264b98ae7f6e3074c5c373
record_format Article
spelling doaj-cf2b3ef699264b98ae7f6e3074c5c3732020-11-25T02:22:57ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1300m130110.1107/S1600536809038422cis-Aquachloridobis(1,10-phenanthroline-κ2N,N′)cobalt(II) chloride 2.5-hydrateK. Arun KumarA. DayalanK. SethuSankarIn the title complex, [CoCl(C12H8N2)2(H2O)]Cl·2.5H2O, the CoII ion is coordinated by four N atoms of two bis-chelating 1,10-phenanthroline (phen) ligands, one water molecule and a chloride ligand in a distorted octahedral environment. The dihedral angle between the two phen ligands is 84.21 (3)°. In the crystal structure, complex molecules and chloride ions are linked into centrosymmetric four-component clusters by intermolecular O—H...Cl hydrogen bonds. Of the 2.5 solvent water molecules in the asymmetric unit, two were refined as disordered over two sites with fixed occupancies of ratios 0.50:0.50 and 0.60:0.40, while another was refined with half occupancy. http://scripts.iucr.org/cgi-bin/paper?S1600536809038422
collection DOAJ
language English
format Article
sources DOAJ
author K. Arun Kumar
A. Dayalan
K. SethuSankar
spellingShingle K. Arun Kumar
A. Dayalan
K. SethuSankar
cis-Aquachloridobis(1,10-phenanthroline-κ2N,N′)cobalt(II) chloride 2.5-hydrate
Acta Crystallographica Section E
author_facet K. Arun Kumar
A. Dayalan
K. SethuSankar
author_sort K. Arun Kumar
title cis-Aquachloridobis(1,10-phenanthroline-κ2N,N′)cobalt(II) chloride 2.5-hydrate
title_short cis-Aquachloridobis(1,10-phenanthroline-κ2N,N′)cobalt(II) chloride 2.5-hydrate
title_full cis-Aquachloridobis(1,10-phenanthroline-κ2N,N′)cobalt(II) chloride 2.5-hydrate
title_fullStr cis-Aquachloridobis(1,10-phenanthroline-κ2N,N′)cobalt(II) chloride 2.5-hydrate
title_full_unstemmed cis-Aquachloridobis(1,10-phenanthroline-κ2N,N′)cobalt(II) chloride 2.5-hydrate
title_sort cis-aquachloridobis(1,10-phenanthroline-κ2n,n′)cobalt(ii) chloride 2.5-hydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description In the title complex, [CoCl(C12H8N2)2(H2O)]Cl·2.5H2O, the CoII ion is coordinated by four N atoms of two bis-chelating 1,10-phenanthroline (phen) ligands, one water molecule and a chloride ligand in a distorted octahedral environment. The dihedral angle between the two phen ligands is 84.21 (3)°. In the crystal structure, complex molecules and chloride ions are linked into centrosymmetric four-component clusters by intermolecular O—H...Cl hydrogen bonds. Of the 2.5 solvent water molecules in the asymmetric unit, two were refined as disordered over two sites with fixed occupancies of ratios 0.50:0.50 and 0.60:0.40, while another was refined with half occupancy.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809038422
work_keys_str_mv AT karunkumar cisaquachloridobis110phenanthrolineamp9542nnamp8242cobaltiichloride25hydrate
AT adayalan cisaquachloridobis110phenanthrolineamp9542nnamp8242cobaltiichloride25hydrate
AT ksethusankar cisaquachloridobis110phenanthrolineamp9542nnamp8242cobaltiichloride25hydrate
_version_ 1724860819988021248

Similar Items