Esterification of acetic acid with alcohol isoamyl in the presence of enzymatic catalyst

The Candida antarctica Lipase B immobilized on polyurethane catalysed esterification of acetic acid with isoamyl alcohol in mechanical and ultrasonic system in a system solvent-free, was studied. The maximum esterification of isoamyl acetate used immobilized catalyst was the highest esterification,...

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Main Authors: Nádia Ligianara Nyari, Alessandro Rogerio Paulazzi, Raquel Vera Zamadei, Jamile Zeni, Rogério Marcos Dallago
Format: Article
Language:Portuguese
Published: Universidade do Oeste de Santa Catarina 2019-12-01
Series:Evidência
Subjects:
Online Access:https://portalperiodicos.unoesc.edu.br/evidencia/article/view/20116
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spelling doaj-cf4d9c9a72c8482a9a3cc2b489a24d212020-11-25T01:59:27ZporUniversidade do Oeste de Santa CatarinaEvidência1519-52872236-60592019-12-0119210.18593/eba.v19i2.2011620116Esterification of acetic acid with alcohol isoamyl in the presence of enzymatic catalystNádia Ligianara NyariAlessandro Rogerio Paulazzi0Raquel Vera Zamadei1Jamile Zeni2Rogério Marcos Dallago3Universidade Regional Integrada do Alto Uruguai e das Missões – URI - Erechim, RS, Brazil.Universidade Regional Integrada do Alto Uruguai e das Missões – URI - Erechim, RS, BrazilUniversidade Regional Integrada do Alto Uruguai e das Missões – URI - Erechim, RS, BrazilUniversidade Regional Integrada do Alto Uruguai e das Missões – URI - Erechim, RS, BrazilThe Candida antarctica Lipase B immobilized on polyurethane catalysed esterification of acetic acid with isoamyl alcohol in mechanical and ultrasonic system in a system solvent-free, was studied. The maximum esterification of isoamyl acetate used immobilized catalyst was the highest esterification, 666.05 U/g with 19 cycles of reuse after 360 minutes of reaction time in mechanical system and 1319.48 U/g was observed and 14 cycles de reuse after 60 minutes of reaction time in ultrasound system. Thus, the process was considered efficient with significant reduction of the reaction time, low instrumental requirements and improve the bioprocess performance. Until now, there were no studies available in the open literature in relation to the ester synthesis catalyzed by immobilized Lipase in polyurethane as support in the ultrasound system. In addition, considered an environmentally correct and economically viable technology, it can be used in cosmetics, pharmaceuticals and food industry. https://portalperiodicos.unoesc.edu.br/evidencia/article/view/20116Candida antarctica Lipase BÉster synthesisIsoamyl acetateBiocatalysis
collection DOAJ
language Portuguese
format Article
sources DOAJ
author Nádia Ligianara Nyari
Alessandro Rogerio Paulazzi
Raquel Vera Zamadei
Jamile Zeni
Rogério Marcos Dallago
spellingShingle Nádia Ligianara Nyari
Alessandro Rogerio Paulazzi
Raquel Vera Zamadei
Jamile Zeni
Rogério Marcos Dallago
Esterification of acetic acid with alcohol isoamyl in the presence of enzymatic catalyst
Evidência
Candida antarctica Lipase B
Éster synthesis
Isoamyl acetate
Biocatalysis
author_facet Nádia Ligianara Nyari
Alessandro Rogerio Paulazzi
Raquel Vera Zamadei
Jamile Zeni
Rogério Marcos Dallago
author_sort Nádia Ligianara Nyari
title Esterification of acetic acid with alcohol isoamyl in the presence of enzymatic catalyst
title_short Esterification of acetic acid with alcohol isoamyl in the presence of enzymatic catalyst
title_full Esterification of acetic acid with alcohol isoamyl in the presence of enzymatic catalyst
title_fullStr Esterification of acetic acid with alcohol isoamyl in the presence of enzymatic catalyst
title_full_unstemmed Esterification of acetic acid with alcohol isoamyl in the presence of enzymatic catalyst
title_sort esterification of acetic acid with alcohol isoamyl in the presence of enzymatic catalyst
publisher Universidade do Oeste de Santa Catarina
series Evidência
issn 1519-5287
2236-6059
publishDate 2019-12-01
description The Candida antarctica Lipase B immobilized on polyurethane catalysed esterification of acetic acid with isoamyl alcohol in mechanical and ultrasonic system in a system solvent-free, was studied. The maximum esterification of isoamyl acetate used immobilized catalyst was the highest esterification, 666.05 U/g with 19 cycles of reuse after 360 minutes of reaction time in mechanical system and 1319.48 U/g was observed and 14 cycles de reuse after 60 minutes of reaction time in ultrasound system. Thus, the process was considered efficient with significant reduction of the reaction time, low instrumental requirements and improve the bioprocess performance. Until now, there were no studies available in the open literature in relation to the ester synthesis catalyzed by immobilized Lipase in polyurethane as support in the ultrasound system. In addition, considered an environmentally correct and economically viable technology, it can be used in cosmetics, pharmaceuticals and food industry.
topic Candida antarctica Lipase B
Éster synthesis
Isoamyl acetate
Biocatalysis
url https://portalperiodicos.unoesc.edu.br/evidencia/article/view/20116
work_keys_str_mv AT nadialigianaranyari esterificationofaceticacidwithalcoholisoamylinthepresenceofenzymaticcatalyst
AT alessandrorogeriopaulazzi esterificationofaceticacidwithalcoholisoamylinthepresenceofenzymaticcatalyst
AT raquelverazamadei esterificationofaceticacidwithalcoholisoamylinthepresenceofenzymaticcatalyst
AT jamilezeni esterificationofaceticacidwithalcoholisoamylinthepresenceofenzymaticcatalyst
AT rogeriomarcosdallago esterificationofaceticacidwithalcoholisoamylinthepresenceofenzymaticcatalyst
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