Summary: | In this studies the influence of the dose and ratio of chemical reagents (Fe<sup>2+</sup> and H<sub>2</sub>O<sub>2</sub>) on the efficiency of COD removal and changes of BOD<sub>5</sub>/COD ratio in landfill leachate was analysed. The molar Fe<sup>2+</sup>/H<sub>2</sub>O<sub>2</sub> ratio was lower than 1 and amounted to: 1:10, 1:5, 1:3, three research series with 1; 2.5 and 5 g/L Fe<sup>2+</sup> concentration. A higher efficiency in removing BOD than COD, and therefore the decrease of BOD<sub>5</sub>/COD ratio in effluent was stated. The efficiency of COD removal from leachate was from 58.34% (Fe<sup>2+</sup> 0.5 g/L, Fe<sup>2+</sup>/H<sub>2</sub>O<sub>2</sub> 1:5) to 8.33% (Fe<sup>2+</sup> = 0.1 g/L, Fe<sup>2+</sup>/H<sub>2</sub>O<sub>2</sub> = 1:10), while the efficiency of BOD removal ranged from 62 to 77%. With the molar ratio Fe<sup>2+</sup>/H<sub>2</sub>O<sub>2</sub> equal 1:5 the BOD<sub>5</sub>/COD ratio was the largest for each of the analysed Fe<sup>2+</sup> doses. The lowest BOD<sub>5</sub>/COD ratio was observed for the Fe<sup>2+</sup> dose 0.1 g/L and molar ratio of reagents 1:3.
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