Dipotassium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)

Dipotassium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)

In the title complex, K2[Co(CH4O6P2)2(H2O)2], the asymmetric unit contains two K+ cations and two half-anions in which the Co atoms lie on inversion centers. The CoII ions assume an octahedral CoO6 coordination geometry. In the crystal, a three-dimensional network is formed through O—H...

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Main Authors: H.G. Visser, J.A. Venter, K.A. Van der Merwe
Format: Article
Language:English
Published: International Union of Crystallography 2010-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S160053680905106X
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spelling doaj-d089a2c24cd84c24a67362d0b11ef9842020-11-25T02:19:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-02-01662m159m15910.1107/S160053680905106XDipotassium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)H.G. VisserJ.A. VenterK.A. Van der MerweIn the title complex, K2[Co(CH4O6P2)2(H2O)2], the asymmetric unit contains two K+ cations and two half-anions in which the Co atoms lie on inversion centers. The CoII ions assume an octahedral CoO6 coordination geometry. In the crystal, a three-dimensional network is formed through O—H...O hydrogen-bond interactions as well as intermolecular interactions between the K+ cations and neighbouring O atoms. http://scripts.iucr.org/cgi-bin/paper?S160053680905106X
collection DOAJ
language English
format Article
sources DOAJ
author H.G. Visser
J.A. Venter
K.A. Van der Merwe
spellingShingle H.G. Visser
J.A. Venter
K.A. Van der Merwe
Dipotassium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
Acta Crystallographica Section E
author_facet H.G. Visser
J.A. Venter
K.A. Van der Merwe
author_sort H.G. Visser
title Dipotassium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
title_short Dipotassium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
title_full Dipotassium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
title_fullStr Dipotassium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
title_full_unstemmed Dipotassium diaquabis(methylenediphosphonato-κ2O,O′)cobaltate(II)
title_sort dipotassium diaquabis(methylenediphosphonato-κ2o,o′)cobaltate(ii)
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2010-02-01
description In the title complex, K2[Co(CH4O6P2)2(H2O)2], the asymmetric unit contains two K+ cations and two half-anions in which the Co atoms lie on inversion centers. The CoII ions assume an octahedral CoO6 coordination geometry. In the crystal, a three-dimensional network is formed through O—H...O hydrogen-bond interactions as well as intermolecular interactions between the K+ cations and neighbouring O atoms.
url http://scripts.iucr.org/cgi-bin/paper?S160053680905106X
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AT javenter dipotassiumdiaquabismethylenediphosphonatoamp9542ooamp8242cobaltateii
AT kavandermerwe dipotassiumdiaquabismethylenediphosphonatoamp9542ooamp8242cobaltateii
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