Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ2N,N′)copper(II)]
In the title complex, [Cu2Cl4(C17H22N2)2], the CuII cation is coordinated by a N,N′-dibenzylpropane-1,2-diamine ligand and two Cl− anions, and a Cl− anion from an adjacent molecule further bridges to the CuII cation in the apical position, with a longer Cu&a...
Main Authors: | , , , |
---|---|
Format: | Article |
Language: | English |
Published: |
International Union of Crystallography
2009-11-01
|
Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809044997 |
Summary: | In the title complex, [Cu2Cl4(C17H22N2)2], the CuII cation is coordinated by a N,N′-dibenzylpropane-1,2-diamine ligand and two Cl− anions, and a Cl− anion from an adjacent molecule further bridges to the CuII cation in the apical position, with a longer Cu—Cl distance of 2.9858 (18) Å, forming a centrosymmetric dimeric complex in which each CuII cation is in a distorted square-pyramidal geometry. Intramolecular N—H...Cl hydrogen bonding is observed in the dimeric complex. |
---|---|
ISSN: | 1600-5368 |