Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ2N,N′)copper(II)]

Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ2N,N′)copper(II)]

In the title complex, [Cu2Cl4(C17H22N2)2], the CuII cation is coordinated by a N,N′-dibenzylpropane-1,2-diamine ligand and two Cl− anions, and a Cl− anion from an adjacent molecule further bridges to the CuII cation in the apical position, with a longer Cu&a...

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Main Authors: Yu-Fen Liu, Da-Fu Rong, Hai-Tao Xia, Da-Qi Wang
Format: Article
Language:English
Published: International Union of Crystallography 2009-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809044997
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spelling doaj-d0e66a40d70740799babe59fad70a7ce2020-11-25T00:54:58ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1492m149210.1107/S1600536809044997Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ2N,N′)copper(II)]Yu-Fen LiuDa-Fu RongHai-Tao XiaDa-Qi WangIn the title complex, [Cu2Cl4(C17H22N2)2], the CuII cation is coordinated by a N,N′-dibenzylpropane-1,2-diamine ligand and two Cl− anions, and a Cl− anion from an adjacent molecule further bridges to the CuII cation in the apical position, with a longer Cu—Cl distance of 2.9858 (18) Å, forming a centrosymmetric dimeric complex in which each CuII cation is in a distorted square-pyramidal geometry. Intramolecular N—H...Cl hydrogen bonding is observed in the dimeric complex. http://scripts.iucr.org/cgi-bin/paper?S1600536809044997
collection DOAJ
language English
format Article
sources DOAJ
author Yu-Fen Liu
Da-Fu Rong
Hai-Tao Xia
Da-Qi Wang
spellingShingle Yu-Fen Liu
Da-Fu Rong
Hai-Tao Xia
Da-Qi Wang
Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ2N,N′)copper(II)]
Acta Crystallographica Section E
author_facet Yu-Fen Liu
Da-Fu Rong
Hai-Tao Xia
Da-Qi Wang
author_sort Yu-Fen Liu
title Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ2N,N′)copper(II)]
title_short Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ2N,N′)copper(II)]
title_full Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ2N,N′)copper(II)]
title_fullStr Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ2N,N′)copper(II)]
title_full_unstemmed Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ2N,N′)copper(II)]
title_sort di-μ-chlorido-bis[chlorido(n,n′-dibenzylpropane-1,2-diamine-κ2n,n′)copper(ii)]
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-11-01
description In the title complex, [Cu2Cl4(C17H22N2)2], the CuII cation is coordinated by a N,N′-dibenzylpropane-1,2-diamine ligand and two Cl− anions, and a Cl− anion from an adjacent molecule further bridges to the CuII cation in the apical position, with a longer Cu—Cl distance of 2.9858 (18) Å, forming a centrosymmetric dimeric complex in which each CuII cation is in a distorted square-pyramidal geometry. Intramolecular N—H...Cl hydrogen bonding is observed in the dimeric complex.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809044997
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AT haitaoxia diamp956chloridobischloridonnamp8242dibenzylpropane12diamineamp9542nnamp8242copperii
AT daqiwang diamp956chloridobischloridonnamp8242dibenzylpropane12diamineamp9542nnamp8242copperii
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