Preparation and Characterization of Smcl3(THF)3 and Sm(BH4)3(THF)3 Complexes
The synthesis of SmCl3(THF)3 from SmCl3.6H2O is described. The reaction of SmCl3(THF)3 with NaBH4 in dry THF gave white microcrystalline tris (tetrahydroborato) tris (tetrahydrofuran) samarium (III), Sm(BH4)3(THF)3. The vibrational and magnetic properties of Sm(BH4)3(THF)3 have been studied.
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| Format: | Article |
| Language: | English |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
1993-12-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
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| Online Access: | http://www.ijcce.ac.ir/article_10394_87e89fa37c5b57cb93b75340637897eb.pdf |
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doaj-d12ecbb3345c49b5a2a1f7d2957a58f62020-11-25T03:41:46ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering 1021-99861021-99861993-12-01122545610394Preparation and Characterization of Smcl3(THF)3 and Sm(BH4)3(THF)3 ComplexesHossein Aghabozorg0Robabeh Alizadeh1Department of Chemistry, Teacher Training University, Tehran, I.R. IRANDepartment of Chemistry, Teacher Training University, Tehran, I.R. IRANThe synthesis of SmCl3(THF)3 from SmCl3.6H2O is described. The reaction of SmCl3(THF)3 with NaBH4 in dry THF gave white microcrystalline tris (tetrahydroborato) tris (tetrahydrofuran) samarium (III), Sm(BH4)3(THF)3. The vibrational and magnetic properties of Sm(BH4)3(THF)3 have been studied.http://www.ijcce.ac.ir/article_10394_87e89fa37c5b57cb93b75340637897eb.pdfsmcl3(thf)3sm(bh4)3(thf)3preparationvibrational spectra |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Hossein Aghabozorg Robabeh Alizadeh |
| spellingShingle |
Hossein Aghabozorg Robabeh Alizadeh Preparation and Characterization of Smcl3(THF)3 and Sm(BH4)3(THF)3 Complexes Iranian Journal of Chemistry & Chemical Engineering smcl3(thf)3 sm(bh4)3(thf)3 preparation vibrational spectra |
| author_facet |
Hossein Aghabozorg Robabeh Alizadeh |
| author_sort |
Hossein Aghabozorg |
| title |
Preparation and Characterization of Smcl3(THF)3 and Sm(BH4)3(THF)3 Complexes |
| title_short |
Preparation and Characterization of Smcl3(THF)3 and Sm(BH4)3(THF)3 Complexes |
| title_full |
Preparation and Characterization of Smcl3(THF)3 and Sm(BH4)3(THF)3 Complexes |
| title_fullStr |
Preparation and Characterization of Smcl3(THF)3 and Sm(BH4)3(THF)3 Complexes |
| title_full_unstemmed |
Preparation and Characterization of Smcl3(THF)3 and Sm(BH4)3(THF)3 Complexes |
| title_sort |
preparation and characterization of smcl3(thf)3 and sm(bh4)3(thf)3 complexes |
| publisher |
Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
| series |
Iranian Journal of Chemistry & Chemical Engineering |
| issn |
1021-9986 1021-9986 |
| publishDate |
1993-12-01 |
| description |
The synthesis of SmCl3(THF)3 from SmCl3.6H2O is described. The reaction of SmCl3(THF)3 with NaBH4 in dry THF gave white microcrystalline tris (tetrahydroborato) tris (tetrahydrofuran) samarium (III), Sm(BH4)3(THF)3. The vibrational and magnetic properties of Sm(BH4)3(THF)3 have been studied. |
| topic |
smcl3(thf)3 sm(bh4)3(thf)3 preparation vibrational spectra |
| url |
http://www.ijcce.ac.ir/article_10394_87e89fa37c5b57cb93b75340637897eb.pdf |
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AT hosseinaghabozorg preparationandcharacterizationofsmcl3thf3andsmbh43thf3complexes AT robabehalizadeh preparationandcharacterizationofsmcl3thf3andsmbh43thf3complexes |
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