INFLUENCE OF MANGANESE ON THE SINTERING PROPERTIES OF TETRAGONAL ZIRCONIA
The influence of small additions of MnO2 (up to 1 wt. %) on the sintering behaviour of yttria-stabilized zirconia sintered over the temperature range from 1250°C to 1500°C was investigated. It was found that the mechanical properties of Y-TZP were dependent on the dopant amount and sintering tempera...
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University of Chemistry and Technology, Prague
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doaj-d17951edcc004dd3b70466c8f20f51e92020-11-24T23:12:53ZengUniversity of Chemistry and Technology, PragueCeramics-Silikáty0862-54681804-58472013-03-015712832INFLUENCE OF MANGANESE ON THE SINTERING PROPERTIES OF TETRAGONAL ZIRCONIAS. RAMESHW.J. KELVIN CHEWC.Y. TANJ. PURBOLAKSONOA.M NOORM.A. HASSANU. SUTHARSINIM. SATGUNAMW.D. TENGThe influence of small additions of MnO2 (up to 1 wt. %) on the sintering behaviour of yttria-stabilized zirconia sintered over the temperature range from 1250°C to 1500°C was investigated. It was found that the mechanical properties of Y-TZP were dependent on the dopant amount and sintering temperature. The results revealed that relative densities above 97.5 % of theoretical (i.e. > 5.95 Mg m-3) could be obtained in Y-TZPs sintered at low temperatures, 1250°C and 1300°C, with the additions of ≥ 0.3 wt. % MnO2. In comparison to the undoped samples, the additions of up to 1 wt. % MnO2 and for sintering up to 1350°C was found to be beneficial in enhancing the Vickers hardness of the ceramic. The fracture toughness of Y-TZP however, was found to increase only in the 1 wt. % MnO2-doped samples when sintered above 1400°C. The relation between the measured mechanical properties is discussed with the emphasis on the role of the manganese oxide.http://www.ceramics-silikaty.cz/2013/pdf/2013_01_028.pdfY-TZPZirconiaManganese OxideMechanical Properties |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
S. RAMESH W.J. KELVIN CHEW C.Y. TAN J. PURBOLAKSONO A.M NOOR M.A. HASSAN U. SUTHARSINI M. SATGUNAM W.D. TENG |
spellingShingle |
S. RAMESH W.J. KELVIN CHEW C.Y. TAN J. PURBOLAKSONO A.M NOOR M.A. HASSAN U. SUTHARSINI M. SATGUNAM W.D. TENG INFLUENCE OF MANGANESE ON THE SINTERING PROPERTIES OF TETRAGONAL ZIRCONIA Ceramics-Silikáty Y-TZP Zirconia Manganese Oxide Mechanical Properties |
author_facet |
S. RAMESH W.J. KELVIN CHEW C.Y. TAN J. PURBOLAKSONO A.M NOOR M.A. HASSAN U. SUTHARSINI M. SATGUNAM W.D. TENG |
author_sort |
S. RAMESH |
title |
INFLUENCE OF MANGANESE ON THE SINTERING PROPERTIES OF TETRAGONAL ZIRCONIA |
title_short |
INFLUENCE OF MANGANESE ON THE SINTERING PROPERTIES OF TETRAGONAL ZIRCONIA |
title_full |
INFLUENCE OF MANGANESE ON THE SINTERING PROPERTIES OF TETRAGONAL ZIRCONIA |
title_fullStr |
INFLUENCE OF MANGANESE ON THE SINTERING PROPERTIES OF TETRAGONAL ZIRCONIA |
title_full_unstemmed |
INFLUENCE OF MANGANESE ON THE SINTERING PROPERTIES OF TETRAGONAL ZIRCONIA |
title_sort |
influence of manganese on the sintering properties of tetragonal zirconia |
publisher |
University of Chemistry and Technology, Prague |
series |
Ceramics-Silikáty |
issn |
0862-5468 1804-5847 |
publishDate |
2013-03-01 |
description |
The influence of small additions of MnO2 (up to 1 wt. %) on the sintering behaviour of yttria-stabilized zirconia sintered over the temperature range from 1250°C to 1500°C was investigated. It was found that the mechanical properties of Y-TZP were dependent on the dopant amount and sintering temperature. The results revealed that relative densities above 97.5 % of theoretical (i.e. > 5.95 Mg m-3) could be obtained in Y-TZPs sintered at low temperatures, 1250°C and 1300°C, with the additions of ≥ 0.3 wt. % MnO2. In comparison to the undoped samples, the additions of up to 1 wt. % MnO2 and for sintering up to 1350°C was found to be beneficial in enhancing the Vickers hardness of the ceramic. The fracture toughness of Y-TZP however, was found to increase only in the 1 wt. % MnO2-doped samples when sintered above 1400°C. The relation between the measured mechanical properties is discussed with the emphasis on the role of the manganese oxide. |
topic |
Y-TZP Zirconia Manganese Oxide Mechanical Properties |
url |
http://www.ceramics-silikaty.cz/2013/pdf/2013_01_028.pdf |
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