Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst
Co-Ag supported on the SiO2 catalyst was synthesized by the sol-gel method and characterized using XRD, FT-IR, TG-DTG, BET, CV, and SEM/EDX analysis. The catalytic performance of the resulting catalyst was examined by the oxidation of mono and sesquiterpenic olefins using hydrogen peroxide and tert-...
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2020-01-01
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doaj-d215a0a12d0548af9d65819a7a4c56272020-11-25T02:26:22ZengHindawi LimitedJournal of Chemistry2090-90632090-90712020-01-01202010.1155/2020/12419521241952Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable CatalystAbderrazak Aberkouks0Ayoub Abdelkader Mekkaoui1Mustapha Ait Ali2Larbi El Firdoussi3Soufiane El Houssame4Laboratoire de Chimie, Modélisation et Sciences de L’Environnement, Université Sultan Moulay Slimane, Faculté Polydisciplinaire de Khouribga, B. P. 145, 25000 Khouribga, MoroccoLaboratoire de Chimie, Modélisation et Sciences de L’Environnement, Université Sultan Moulay Slimane, Faculté Polydisciplinaire de Khouribga, B. P. 145, 25000 Khouribga, MoroccoLaboratoire de Chimie de Coordination et de Catalyse, Département de Chimie, Faculté des Sciences Semlalia, B. P. 2390, 40001 Marrakech, MoroccoLaboratoire de Chimie de Coordination et de Catalyse, Département de Chimie, Faculté des Sciences Semlalia, B. P. 2390, 40001 Marrakech, MoroccoLaboratoire de Chimie, Modélisation et Sciences de L’Environnement, Université Sultan Moulay Slimane, Faculté Polydisciplinaire de Khouribga, B. P. 145, 25000 Khouribga, MoroccoCo-Ag supported on the SiO2 catalyst was synthesized by the sol-gel method and characterized using XRD, FT-IR, TG-DTG, BET, CV, and SEM/EDX analysis. The catalytic performance of the resulting catalyst was examined by the oxidation of mono and sesquiterpenic olefins using hydrogen peroxide and tert-butyl peroxide as oxidant agents. Various parameters such as catalyst amount, temperature, and solvents have been studied. The Co-Ag supported on the SiO2 catalyst showed a high activity, selectivity, and recyclability for the selected oxidation reaction.http://dx.doi.org/10.1155/2020/1241952 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Abderrazak Aberkouks Ayoub Abdelkader Mekkaoui Mustapha Ait Ali Larbi El Firdoussi Soufiane El Houssame |
spellingShingle |
Abderrazak Aberkouks Ayoub Abdelkader Mekkaoui Mustapha Ait Ali Larbi El Firdoussi Soufiane El Houssame Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst Journal of Chemistry |
author_facet |
Abderrazak Aberkouks Ayoub Abdelkader Mekkaoui Mustapha Ait Ali Larbi El Firdoussi Soufiane El Houssame |
author_sort |
Abderrazak Aberkouks |
title |
Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst |
title_short |
Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst |
title_full |
Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst |
title_fullStr |
Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst |
title_full_unstemmed |
Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst |
title_sort |
selective allylic oxidation of terpenic olefins using co-ag supported on sio2 as a novel, efficient, and recyclable catalyst |
publisher |
Hindawi Limited |
series |
Journal of Chemistry |
issn |
2090-9063 2090-9071 |
publishDate |
2020-01-01 |
description |
Co-Ag supported on the SiO2 catalyst was synthesized by the sol-gel method and characterized using XRD, FT-IR, TG-DTG, BET, CV, and SEM/EDX analysis. The catalytic performance of the resulting catalyst was examined by the oxidation of mono and sesquiterpenic olefins using hydrogen peroxide and tert-butyl peroxide as oxidant agents. Various parameters such as catalyst amount, temperature, and solvents have been studied. The Co-Ag supported on the SiO2 catalyst showed a high activity, selectivity, and recyclability for the selected oxidation reaction. |
url |
http://dx.doi.org/10.1155/2020/1241952 |
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