Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst

Co-Ag supported on the SiO2 catalyst was synthesized by the sol-gel method and characterized using XRD, FT-IR, TG-DTG, BET, CV, and SEM/EDX analysis. The catalytic performance of the resulting catalyst was examined by the oxidation of mono and sesquiterpenic olefins using hydrogen peroxide and tert-...

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Main Authors: Abderrazak Aberkouks, Ayoub Abdelkader Mekkaoui, Mustapha Ait Ali, Larbi El Firdoussi, Soufiane El Houssame
Format: Article
Language:English
Published: Hindawi Limited 2020-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2020/1241952
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spelling doaj-d215a0a12d0548af9d65819a7a4c56272020-11-25T02:26:22ZengHindawi LimitedJournal of Chemistry2090-90632090-90712020-01-01202010.1155/2020/12419521241952Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable CatalystAbderrazak Aberkouks0Ayoub Abdelkader Mekkaoui1Mustapha Ait Ali2Larbi El Firdoussi3Soufiane El Houssame4Laboratoire de Chimie, Modélisation et Sciences de L’Environnement, Université Sultan Moulay Slimane, Faculté Polydisciplinaire de Khouribga, B. P. 145, 25000 Khouribga, MoroccoLaboratoire de Chimie, Modélisation et Sciences de L’Environnement, Université Sultan Moulay Slimane, Faculté Polydisciplinaire de Khouribga, B. P. 145, 25000 Khouribga, MoroccoLaboratoire de Chimie de Coordination et de Catalyse, Département de Chimie, Faculté des Sciences Semlalia, B. P. 2390, 40001 Marrakech, MoroccoLaboratoire de Chimie de Coordination et de Catalyse, Département de Chimie, Faculté des Sciences Semlalia, B. P. 2390, 40001 Marrakech, MoroccoLaboratoire de Chimie, Modélisation et Sciences de L’Environnement, Université Sultan Moulay Slimane, Faculté Polydisciplinaire de Khouribga, B. P. 145, 25000 Khouribga, MoroccoCo-Ag supported on the SiO2 catalyst was synthesized by the sol-gel method and characterized using XRD, FT-IR, TG-DTG, BET, CV, and SEM/EDX analysis. The catalytic performance of the resulting catalyst was examined by the oxidation of mono and sesquiterpenic olefins using hydrogen peroxide and tert-butyl peroxide as oxidant agents. Various parameters such as catalyst amount, temperature, and solvents have been studied. The Co-Ag supported on the SiO2 catalyst showed a high activity, selectivity, and recyclability for the selected oxidation reaction.http://dx.doi.org/10.1155/2020/1241952
collection DOAJ
language English
format Article
sources DOAJ
author Abderrazak Aberkouks
Ayoub Abdelkader Mekkaoui
Mustapha Ait Ali
Larbi El Firdoussi
Soufiane El Houssame
spellingShingle Abderrazak Aberkouks
Ayoub Abdelkader Mekkaoui
Mustapha Ait Ali
Larbi El Firdoussi
Soufiane El Houssame
Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst
Journal of Chemistry
author_facet Abderrazak Aberkouks
Ayoub Abdelkader Mekkaoui
Mustapha Ait Ali
Larbi El Firdoussi
Soufiane El Houssame
author_sort Abderrazak Aberkouks
title Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst
title_short Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst
title_full Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst
title_fullStr Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst
title_full_unstemmed Selective Allylic Oxidation of Terpenic Olefins Using Co-Ag Supported on SiO2 as a Novel, Efficient, and Recyclable Catalyst
title_sort selective allylic oxidation of terpenic olefins using co-ag supported on sio2 as a novel, efficient, and recyclable catalyst
publisher Hindawi Limited
series Journal of Chemistry
issn 2090-9063
2090-9071
publishDate 2020-01-01
description Co-Ag supported on the SiO2 catalyst was synthesized by the sol-gel method and characterized using XRD, FT-IR, TG-DTG, BET, CV, and SEM/EDX analysis. The catalytic performance of the resulting catalyst was examined by the oxidation of mono and sesquiterpenic olefins using hydrogen peroxide and tert-butyl peroxide as oxidant agents. Various parameters such as catalyst amount, temperature, and solvents have been studied. The Co-Ag supported on the SiO2 catalyst showed a high activity, selectivity, and recyclability for the selected oxidation reaction.
url http://dx.doi.org/10.1155/2020/1241952
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