Electron and hydrogen self-exchange of free radicals of sterically hindered tertiary aliphatic amines investigated by photo-CIDNP

Electron and hydrogen self-exchange of free radicals of sterically hindered tertiary aliphatic amines investigated by photo-CIDNP

The photoreactions of diazabicyclo[2,2,2]octane (DABCO) and triisopropylamine (TIPA) with the sensitizers anthraquinone (AQ) and xanthone (XA) or benzophenone (BP) were investigated by time-resolved photo-CIDNP (photochemically induced dynamic nuclear polarization) experiments. By varying the radica...

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Bibliographic Details
Main Authors: Martin Goez, Isabell Frisch, Ingo Sartorius
Format: Article
Language:English
Published: Beilstein-Institut 2013-02-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
amines
CIDNP
electron transfer
free radicals
hydrogen transfer
ketones
kinetics
photochemistry
self-exchange
Online Access:https://doi.org/10.3762/bjoc.9.46

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