Synthesis of Linseed Oil-Based Waterborne Urethane Oil Wood Coatings
The linseed oil glyceride (LOG) was synthesized by using a transesterification process with a glycerol/linseed oil molar ratio of 1.0. The waterborne urethane oil (WUO) wood coating was prepared by acetone process. First, dimethylolpropionic acid was reacted with hexamethylene diisocyanate (HDI) or...
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doaj-d53b288b158b45b29936becf3d7644fd2020-11-24T20:56:25ZengMDPI AGPolymers2073-43602018-11-011011123510.3390/polym10111235polym10111235Synthesis of Linseed Oil-Based Waterborne Urethane Oil Wood CoatingsChia-Wei Chang0Jing-Ping Chang1Kun-Tsung Lu2Department of Forestry, National Chung Hsing University, 250, Kuo-Kuang Rd., Taichung 402, TaiwanDepartment of Forestry, National Chung Hsing University, 250, Kuo-Kuang Rd., Taichung 402, TaiwanDepartment of Forestry, National Chung Hsing University, 250, Kuo-Kuang Rd., Taichung 402, TaiwanThe linseed oil glyceride (LOG) was synthesized by using a transesterification process with a glycerol/linseed oil molar ratio of 1.0. The waterborne urethane oil (WUO) wood coating was prepared by acetone process. First, dimethylolpropionic acid was reacted with hexamethylene diisocyanate (HDI) or isophorone diisocyanate (IPDI), followed by adding LOG at various NCO/OH molars of 0.7, 0.8, and 0.9, respectively, and the COOH-containing prepolymer was obtained. Then, the ionomer which was prepared by neutralizing prepolymer with trimethylamine, was dispersed by adding deionized water, and the water⁻acetone dispersion was obtained. Finally, the acetone was removed by vacuum distillation. In the whole synthesized process, the LOG and COOH-containing prepolymer could be steadily synthesized by FTIR analysis, and the weight-average molecular weight and polydispersity of COOH-containing prepolymer increased with an increase of NCO/OH molar ratios. During the water dispersion process of the ionomer acetone solution, the point of phase inversion was prolonged, meaning the solid content decreased with an increase of NCO/OH molar ratios. After acetone was removed, the color of WUO was milky-white, and it was weakly alkaline and possessed a pseudoplastic fluid behavior. The particle size of WUO increased with increasing of NCO/OH molar ratios, however, the storage stability was extended for HDI and shortened for IPDI synthesized with increasing of NCO/OH molar ratios.https://www.mdpi.com/2073-4360/10/11/1235linseed oilacetone processwaterborne urethane oilwood coatings |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Chia-Wei Chang Jing-Ping Chang Kun-Tsung Lu |
spellingShingle |
Chia-Wei Chang Jing-Ping Chang Kun-Tsung Lu Synthesis of Linseed Oil-Based Waterborne Urethane Oil Wood Coatings Polymers linseed oil acetone process waterborne urethane oil wood coatings |
author_facet |
Chia-Wei Chang Jing-Ping Chang Kun-Tsung Lu |
author_sort |
Chia-Wei Chang |
title |
Synthesis of Linseed Oil-Based Waterborne Urethane Oil Wood Coatings |
title_short |
Synthesis of Linseed Oil-Based Waterborne Urethane Oil Wood Coatings |
title_full |
Synthesis of Linseed Oil-Based Waterborne Urethane Oil Wood Coatings |
title_fullStr |
Synthesis of Linseed Oil-Based Waterborne Urethane Oil Wood Coatings |
title_full_unstemmed |
Synthesis of Linseed Oil-Based Waterborne Urethane Oil Wood Coatings |
title_sort |
synthesis of linseed oil-based waterborne urethane oil wood coatings |
publisher |
MDPI AG |
series |
Polymers |
issn |
2073-4360 |
publishDate |
2018-11-01 |
description |
The linseed oil glyceride (LOG) was synthesized by using a transesterification process with a glycerol/linseed oil molar ratio of 1.0. The waterborne urethane oil (WUO) wood coating was prepared by acetone process. First, dimethylolpropionic acid was reacted with hexamethylene diisocyanate (HDI) or isophorone diisocyanate (IPDI), followed by adding LOG at various NCO/OH molars of 0.7, 0.8, and 0.9, respectively, and the COOH-containing prepolymer was obtained. Then, the ionomer which was prepared by neutralizing prepolymer with trimethylamine, was dispersed by adding deionized water, and the water⁻acetone dispersion was obtained. Finally, the acetone was removed by vacuum distillation. In the whole synthesized process, the LOG and COOH-containing prepolymer could be steadily synthesized by FTIR analysis, and the weight-average molecular weight and polydispersity of COOH-containing prepolymer increased with an increase of NCO/OH molar ratios. During the water dispersion process of the ionomer acetone solution, the point of phase inversion was prolonged, meaning the solid content decreased with an increase of NCO/OH molar ratios. After acetone was removed, the color of WUO was milky-white, and it was weakly alkaline and possessed a pseudoplastic fluid behavior. The particle size of WUO increased with increasing of NCO/OH molar ratios, however, the storage stability was extended for HDI and shortened for IPDI synthesized with increasing of NCO/OH molar ratios. |
topic |
linseed oil acetone process waterborne urethane oil wood coatings |
url |
https://www.mdpi.com/2073-4360/10/11/1235 |
work_keys_str_mv |
AT chiaweichang synthesisoflinseedoilbasedwaterborneurethaneoilwoodcoatings AT jingpingchang synthesisoflinseedoilbasedwaterborneurethaneoilwoodcoatings AT kuntsunglu synthesisoflinseedoilbasedwaterborneurethaneoilwoodcoatings |
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1716789782794731520 |