Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate

Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate

In the cation of the title compound, [Mn(C11H13N5)2](ClO4)2·CH3CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms of...

Full description

Bibliographic Details
Main Authors: Shao-Ming Shang, Chun-Xia Ren, Xin Wang, Lu-De Lu, Xu-Jie Yang
Format: Article
Language:English
Published: International Union of Crystallography 2009-09-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809029195
id doaj-d56ea92e05d64dad9b2e0478cd04129d
record_format Article
spelling doaj-d56ea92e05d64dad9b2e0478cd04129d2020-11-25T00:51:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-09-01659m1023m102410.1107/S1600536809029195Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvateShao-Ming ShangChun-Xia RenXin WangLu-De LuXu-Jie YangIn the cation of the title compound, [Mn(C11H13N5)2](ClO4)2·CH3CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms of the perchlorate anions are disordered with occupancies in the ratio 0.593 (10):0.407 (10). In the crystal, molecules are stabilized by two N—H...O hydrogen bonds, forming zigzag chains along the a axis, which are further interconnected by N—H...O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.50 (1) Å] into a three-dimensional network. http://scripts.iucr.org/cgi-bin/paper?S1600536809029195
collection DOAJ
language English
format Article
sources DOAJ
author Shao-Ming Shang
Chun-Xia Ren
Xin Wang
Lu-De Lu
Xu-Jie Yang
spellingShingle Shao-Ming Shang
Chun-Xia Ren
Xin Wang
Lu-De Lu
Xu-Jie Yang
Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate
Acta Crystallographica Section E
author_facet Shao-Ming Shang
Chun-Xia Ren
Xin Wang
Lu-De Lu
Xu-Jie Yang
author_sort Shao-Ming Shang
title Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate
title_short Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate
title_full Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate
title_fullStr Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate
title_full_unstemmed Bis[2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine]manganese(II) bis(perchlorate) acetonitrile solvate
title_sort bis[2,6-bis(4,5-dihydro-1h-imidazol-2-yl)pyridine]manganese(ii) bis(perchlorate) acetonitrile solvate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2009-09-01
description In the cation of the title compound, [Mn(C11H13N5)2](ClO4)2·CH3CN, the metal atom is located on a twofold rotation axis and is six-coordinated by six N atoms from two different 2,6-bis(4,5-dihydro-1H-imidazol-2-yl)pyridine (bip) ligands in a distorted octahedral geometry. The O atoms of the perchlorate anions are disordered with occupancies in the ratio 0.593 (10):0.407 (10). In the crystal, molecules are stabilized by two N—H...O hydrogen bonds, forming zigzag chains along the a axis, which are further interconnected by N—H...O hydrogen bonds and π–π interactions [centroid–centroid distance = 3.50 (1) Å] into a three-dimensional network.
url http://scripts.iucr.org/cgi-bin/paper?S1600536809029195
work_keys_str_mv AT shaomingshang bis26bis45dihydro1himidazol2ylpyridinemanganeseiibisperchlorateacetonitrilesolvate
AT chunxiaren bis26bis45dihydro1himidazol2ylpyridinemanganeseiibisperchlorateacetonitrilesolvate
AT xinwang bis26bis45dihydro1himidazol2ylpyridinemanganeseiibisperchlorateacetonitrilesolvate
AT ludelu bis26bis45dihydro1himidazol2ylpyridinemanganeseiibisperchlorateacetonitrilesolvate
AT xujieyang bis26bis45dihydro1himidazol2ylpyridinemanganeseiibisperchlorateacetonitrilesolvate
_version_ 1725245787686830080

Similar Items