6-(2-Chlorobenzylamino)purinium tetrachlorido(dimethyl sulfoxide-κO)(nitrosyl-κN)ruthenate(III) monohydrate

6-(2-Chlorobenzylamino)purinium tetrachlorido(dimethyl sulfoxide-κO)(nitrosyl-κN)ruthenate(III) monohydrate

The asymmetric unit of the title complex salt, (C12H11ClN5)[RuCl4(NO)(C2H6OS)]·H2O, contains a 6-(2-chlorobenzylamino)purinium cation, a tetrachlorido(dimethyl sulfoxide)nitrosylruthenate(III) anion and one solvent water molecule. The RuIII atom is octahedrally coordinated by four Cl atoms...

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Main Authors: Kamila Štěpánková, Miroslava Matiková-Maľarová, Zdeněk Trávníček
Format: Article
Language:English
Published: International Union of Crystallography 2008-04-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808006673
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spelling doaj-d627542875da48da9ea800572a61cc2a2020-11-24T22:08:40ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-04-01644m545m54610.1107/S16005368080066736-(2-Chlorobenzylamino)purinium tetrachlorido(dimethyl sulfoxide-κO)(nitrosyl-κN)ruthenate(III) monohydrateKamila ŠtěpánkováMiroslava Matiková-MaľarováZdeněk TrávníčekThe asymmetric unit of the title complex salt, (C12H11ClN5)[RuCl4(NO)(C2H6OS)]·H2O, contains a 6-(2-chlorobenzylamino)purinium cation, a tetrachlorido(dimethyl sulfoxide)nitrosylruthenate(III) anion and one solvent water molecule. The RuIII atom is octahedrally coordinated by four Cl atoms in the equatorial plane, and by a dimethyl sulfoxide O atom and a nitrosyl N atom in axial positions. The cation is an N3-protonated N7 tautomer. Intermolecular N–H...N hydrogen bonds connect two cations into centrosymmetric dimers, with an N...N distance of 2.821 (4) Å. The crystal structure also involves N—H...O, N—H...Cl and O—H...Cl hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536808006673
collection DOAJ
language English
format Article
sources DOAJ
author Kamila Štěpánková
Miroslava Matiková-Maľarová
Zdeněk Trávníček
spellingShingle Kamila Štěpánková
Miroslava Matiková-Maľarová
Zdeněk Trávníček
6-(2-Chlorobenzylamino)purinium tetrachlorido(dimethyl sulfoxide-κO)(nitrosyl-κN)ruthenate(III) monohydrate
Acta Crystallographica Section E
author_facet Kamila Štěpánková
Miroslava Matiková-Maľarová
Zdeněk Trávníček
author_sort Kamila Štěpánková
title 6-(2-Chlorobenzylamino)purinium tetrachlorido(dimethyl sulfoxide-κO)(nitrosyl-κN)ruthenate(III) monohydrate
title_short 6-(2-Chlorobenzylamino)purinium tetrachlorido(dimethyl sulfoxide-κO)(nitrosyl-κN)ruthenate(III) monohydrate
title_full 6-(2-Chlorobenzylamino)purinium tetrachlorido(dimethyl sulfoxide-κO)(nitrosyl-κN)ruthenate(III) monohydrate
title_fullStr 6-(2-Chlorobenzylamino)purinium tetrachlorido(dimethyl sulfoxide-κO)(nitrosyl-κN)ruthenate(III) monohydrate
title_full_unstemmed 6-(2-Chlorobenzylamino)purinium tetrachlorido(dimethyl sulfoxide-κO)(nitrosyl-κN)ruthenate(III) monohydrate
title_sort 6-(2-chlorobenzylamino)purinium tetrachlorido(dimethyl sulfoxide-κo)(nitrosyl-κn)ruthenate(iii) monohydrate
publisher International Union of Crystallography
series Acta Crystallographica Section E
issn 1600-5368
publishDate 2008-04-01
description The asymmetric unit of the title complex salt, (C12H11ClN5)[RuCl4(NO)(C2H6OS)]·H2O, contains a 6-(2-chlorobenzylamino)purinium cation, a tetrachlorido(dimethyl sulfoxide)nitrosylruthenate(III) anion and one solvent water molecule. The RuIII atom is octahedrally coordinated by four Cl atoms in the equatorial plane, and by a dimethyl sulfoxide O atom and a nitrosyl N atom in axial positions. The cation is an N3-protonated N7 tautomer. Intermolecular N–H...N hydrogen bonds connect two cations into centrosymmetric dimers, with an N...N distance of 2.821 (4) Å. The crystal structure also involves N—H...O, N—H...Cl and O—H...Cl hydrogen bonds.
url http://scripts.iucr.org/cgi-bin/paper?S1600536808006673
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AT miroslavamatikov225ma318arov225 62chlorobenzylaminopuriniumtetrachloridodimethylsulfoxide954onitrosyl954nruthenateiiimonohydrate
AT zden283ktr225vn237269ek 62chlorobenzylaminopuriniumtetrachloridodimethylsulfoxide954onitrosyl954nruthenateiiimonohydrate
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