{rac-5-[Methoxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(II)
The title compound, [Ni(C40H28N4O)], was obtained from a Grignard reaction of the respective formylporphyrin to yield {5-[hydroxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(II), followed by crystallization from methylene chloride/methanol. The molecule exhibits a ruffled macrocycle with an ave...
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International Union of Crystallography
2011-02-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811002960 |
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doaj-d630980cbd41461482feb33e52edd6672020-11-24T20:56:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672m265m26510.1107/S1600536811002960{rac-5-[Methoxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(II)Mathias O. SengeKatja DahmsThe title compound, [Ni(C40H28N4O)], was obtained from a Grignard reaction of the respective formylporphyrin to yield {5-[hydroxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(II), followed by crystallization from methylene chloride/methanol. The molecule exhibits a ruffled macrocycle with an average deviation of the 24 macrocycle atoms from their least-squares plane (Δ24) of 0.26 Å and an average Ni—N bond length of 1.931 (2) Å. In line with the asymmetrical substituent pattern, the degree of distortion is slightly larger at point of attachment of the methoxy(phenyl)methyl residue than at the unsubstituted meso position. The methoxy group attached to the chiral C atom is disordered in a 0.534 (4):0.466 (4) ratio. http://scripts.iucr.org/cgi-bin/paper?S1600536811002960 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Mathias O. Senge Katja Dahms |
spellingShingle |
Mathias O. Senge Katja Dahms {rac-5-[Methoxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(II) Acta Crystallographica Section E |
author_facet |
Mathias O. Senge Katja Dahms |
author_sort |
Mathias O. Senge |
title |
{rac-5-[Methoxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(II) |
title_short |
{rac-5-[Methoxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(II) |
title_full |
{rac-5-[Methoxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(II) |
title_fullStr |
{rac-5-[Methoxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(II) |
title_full_unstemmed |
{rac-5-[Methoxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(II) |
title_sort |
{rac-5-[methoxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(ii) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2011-02-01 |
description |
The title compound, [Ni(C40H28N4O)], was obtained from a Grignard reaction of the respective formylporphyrin to yield {5-[hydroxy(phenyl)methyl]-10,20-diphenylporphyrinato}nickel(II), followed by crystallization from methylene chloride/methanol. The molecule exhibits a ruffled macrocycle with an average deviation of the 24 macrocycle atoms from their least-squares plane (Δ24) of 0.26 Å and an average Ni—N bond length of 1.931 (2) Å. In line with the asymmetrical substituent pattern, the degree of distortion is slightly larger at point of attachment of the methoxy(phenyl)methyl residue than at the unsubstituted meso position. The methoxy group attached to the chiral C atom is disordered in a 0.534 (4):0.466 (4) ratio. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536811002960 |
work_keys_str_mv |
AT mathiasosenge rac5methoxyphenylmethyl1020diphenylporphyrinatonickelii AT katjadahms rac5methoxyphenylmethyl1020diphenylporphyrinatonickelii |
_version_ |
1716790503700168704 |