{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I)
In the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the CuI ion is coordinated by two triphenylphosphane molecules and two O atoms of the chelating dimethyl(phenylsulfonyl)amidophosphate anion, generating a squashed CuO2P2 tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost...
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International Union of Crystallography
2014-06-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814010095 |
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doaj-d731154dcfba42ddbaebc73875e1fbce2020-11-24T22:09:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-06-01706m209m21010.1107/S1600536814010095hb7222{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I)Olesia V. Moroz0Viktor A. Trush1Tatiana Yu. Sliva2Kateryna O. Znovjyak3Vladimir M. Amirkhanov4Taras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineTaras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineTaras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineTaras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineTaras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineIn the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the CuI ion is coordinated by two triphenylphosphane molecules and two O atoms of the chelating dimethyl(phenylsulfonyl)amidophosphate anion, generating a squashed CuO2P2 tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost coplanar (r.m.s. deviation = 0.024 Å), with the N and S atoms displaced in the same direction, by 0.708 (5) and 0.429 (2) Å, respectively.http://scripts.iucr.org/cgi-bin/paper?S1600536814010095 |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Olesia V. Moroz Viktor A. Trush Tatiana Yu. Sliva Kateryna O. Znovjyak Vladimir M. Amirkhanov |
spellingShingle |
Olesia V. Moroz Viktor A. Trush Tatiana Yu. Sliva Kateryna O. Znovjyak Vladimir M. Amirkhanov {Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I) Acta Crystallographica Section E |
author_facet |
Olesia V. Moroz Viktor A. Trush Tatiana Yu. Sliva Kateryna O. Znovjyak Vladimir M. Amirkhanov |
author_sort |
Olesia V. Moroz |
title |
{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I) |
title_short |
{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I) |
title_full |
{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I) |
title_fullStr |
{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I) |
title_full_unstemmed |
{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I) |
title_sort |
{dimethyl [(phenylsulfonyl)amido]phosphato-κ2o,o′}bis(triphenylphosphane-κp)copper(i) |
publisher |
International Union of Crystallography |
series |
Acta Crystallographica Section E |
issn |
1600-5368 |
publishDate |
2014-06-01 |
description |
In the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the CuI ion is coordinated by two triphenylphosphane molecules and two O atoms of the chelating dimethyl(phenylsulfonyl)amidophosphate anion, generating a squashed CuO2P2 tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost coplanar (r.m.s. deviation = 0.024 Å), with the N and S atoms displaced in the same direction, by 0.708 (5) and 0.429 (2) Å, respectively. |
url |
http://scripts.iucr.org/cgi-bin/paper?S1600536814010095 |
work_keys_str_mv |
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1725810105705824256 |