{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I)

In the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the CuI ion is coordinated by two triphenylphosphane molecules and two O atoms of the chelating dimethyl(phenylsulfonyl)amidophosphate anion, generating a squashed CuO2P2 tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost...

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Main Authors:	Olesia V. Moroz, Viktor A. Trush, Tatiana Yu. Sliva, Kateryna O. Znovjyak, Vladimir M. Amirkhanov
Format:	Article
Language:	English
Published:	International Union of Crystallography 2014-06-01
Series:	Acta Crystallographica Section E
Online Access:	http://scripts.iucr.org/cgi-bin/paper?S1600536814010095

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spelling	doaj-d731154dcfba42ddbaebc73875e1fbce2020-11-24T22:09:54ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-06-01706m209m21010.1107/S1600536814010095hb7222{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I)Olesia V. Moroz0Viktor A. Trush1Tatiana Yu. Sliva2Kateryna O. Znovjyak3Vladimir M. Amirkhanov4Taras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineTaras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineTaras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineTaras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineTaras Shevchenko National University of Kyiv, Department of Chemistry, 64/13 Volodymyrska Street, Kyiv 01601, UkraineIn the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the CuI ion is coordinated by two triphenylphosphane molecules and two O atoms of the chelating dimethyl(phenylsulfonyl)amidophosphate anion, generating a squashed CuO2P2 tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost coplanar (r.m.s. deviation = 0.024 Å), with the N and S atoms displaced in the same direction, by 0.708 (5) and 0.429 (2) Å, respectively.http://scripts.iucr.org/cgi-bin/paper?S1600536814010095
collection	DOAJ
language	English
format	Article
sources	DOAJ
author	Olesia V. Moroz Viktor A. Trush Tatiana Yu. Sliva Kateryna O. Znovjyak Vladimir M. Amirkhanov
spellingShingle	Olesia V. Moroz Viktor A. Trush Tatiana Yu. Sliva Kateryna O. Znovjyak Vladimir M. Amirkhanov {Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I) Acta Crystallographica Section E
author_facet	Olesia V. Moroz Viktor A. Trush Tatiana Yu. Sliva Kateryna O. Znovjyak Vladimir M. Amirkhanov
author_sort	Olesia V. Moroz
title	{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I)
title_short	{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I)
title_full	{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I)
title_fullStr	{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I)
title_full_unstemmed	{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I)
title_sort	{dimethyl [(phenylsulfonyl)amido]phosphato-κ2o,o′}bis(triphenylphosphane-κp)copper(i)
publisher	International Union of Crystallography
series	Acta Crystallographica Section E
issn	1600-5368
publishDate	2014-06-01
description	In the title complex, [Cu(C8H11NO5PS)(C18H15P)2], the CuI ion is coordinated by two triphenylphosphane molecules and two O atoms of the chelating dimethyl(phenylsulfonyl)amidophosphate anion, generating a squashed CuO2P2 tetrahedron. In the six-membered chelate ring, the Cu, P and O atoms are almost coplanar (r.m.s. deviation = 0.024 Å), with the N and S atoms displaced in the same direction, by 0.708 (5) and 0.429 (2) Å, respectively.
url	http://scripts.iucr.org/cgi-bin/paper?S1600536814010095
work_keys_str_mv	AT olesiavmoroz dimethylphenylsulfonylamidophosphatok2oobistriphenylphosphanekpcopperi AT viktoratrush dimethylphenylsulfonylamidophosphatok2oobistriphenylphosphanekpcopperi AT tatianayusliva dimethylphenylsulfonylamidophosphatok2oobistriphenylphosphanekpcopperi AT katerynaoznovjyak dimethylphenylsulfonylamidophosphatok2oobistriphenylphosphanekpcopperi AT vladimirmamirkhanov dimethylphenylsulfonylamidophosphatok2oobistriphenylphosphanekpcopperi
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{Dimethyl [(phenylsulfonyl)amido]phosphato-κ2O,O′}bis(triphenylphosphane-κP)copper(I)

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