fac-Triaqua(2,2′-bipyridine-κ2N,N′)(nitrato-κO)cobalt(II) chloride
The asymmetric unit of the title complex, [Co(NO3)(C10H8N2)(H2O)3]Cl, consists of a chloride anion and a complex cation, which is built on a monodentate nitrate anion, three water molecules and one bidentate 2,2′-bipyridine molecule, coordinated to a CoII cation, in a distorted octahedral geometry....
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International Union of Crystallography
2018-06-01
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doaj-d7850edc477244e09edb287c26fedfc12020-11-24T23:41:42ZengInternational Union of CrystallographyIUCrData2414-31462018-06-0136x18086510.1107/S2414314618008660bv4017fac-Triaqua(2,2′-bipyridine-κ2N,N′)(nitrato-κO)cobalt(II) chlorideMouhamadou Birame Diop0Libasse Diop1Sylvain Bernès2Laboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalLaboratoire de Chimie Minérale et Analytique, Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, SenegalInstituto de Física, Benemérita Universidad Autónoma de Puebla, Av. San Claudio y 18 Sur, 72570 Puebla, Pue., MexicoThe asymmetric unit of the title complex, [Co(NO3)(C10H8N2)(H2O)3]Cl, consists of a chloride anion and a complex cation, which is built on a monodentate nitrate anion, three water molecules and one bidentate 2,2′-bipyridine molecule, coordinated to a CoII cation, in a distorted octahedral geometry. The water molecules are arranged in a facial geometry, and serve as donors for hydrogen bonding. Acceptor sites in the crystal are chloride ions and one O atom of the coordinating nitrate ion. A three-dimensional framework is formed, based on O—H...O and O—H...Cl contacts.http://scripts.iucr.org/cgi-bin/paper?S2414314618008660crystal structurecobaltnitrate2,2′-bipyridinesupramolecular interactions |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Mouhamadou Birame Diop Libasse Diop Sylvain Bernès |
spellingShingle |
Mouhamadou Birame Diop Libasse Diop Sylvain Bernès fac-Triaqua(2,2′-bipyridine-κ2N,N′)(nitrato-κO)cobalt(II) chloride IUCrData crystal structure cobalt nitrate 2,2′-bipyridine supramolecular interactions |
author_facet |
Mouhamadou Birame Diop Libasse Diop Sylvain Bernès |
author_sort |
Mouhamadou Birame Diop |
title |
fac-Triaqua(2,2′-bipyridine-κ2N,N′)(nitrato-κO)cobalt(II) chloride |
title_short |
fac-Triaqua(2,2′-bipyridine-κ2N,N′)(nitrato-κO)cobalt(II) chloride |
title_full |
fac-Triaqua(2,2′-bipyridine-κ2N,N′)(nitrato-κO)cobalt(II) chloride |
title_fullStr |
fac-Triaqua(2,2′-bipyridine-κ2N,N′)(nitrato-κO)cobalt(II) chloride |
title_full_unstemmed |
fac-Triaqua(2,2′-bipyridine-κ2N,N′)(nitrato-κO)cobalt(II) chloride |
title_sort |
fac-triaqua(2,2′-bipyridine-κ2n,n′)(nitrato-κo)cobalt(ii) chloride |
publisher |
International Union of Crystallography |
series |
IUCrData |
issn |
2414-3146 |
publishDate |
2018-06-01 |
description |
The asymmetric unit of the title complex, [Co(NO3)(C10H8N2)(H2O)3]Cl, consists of a chloride anion and a complex cation, which is built on a monodentate nitrate anion, three water molecules and one bidentate 2,2′-bipyridine molecule, coordinated to a CoII cation, in a distorted octahedral geometry. The water molecules are arranged in a facial geometry, and serve as donors for hydrogen bonding. Acceptor sites in the crystal are chloride ions and one O atom of the coordinating nitrate ion. A three-dimensional framework is formed, based on O—H...O and O—H...Cl contacts. |
topic |
crystal structure cobalt nitrate 2,2′-bipyridine supramolecular interactions |
url |
http://scripts.iucr.org/cgi-bin/paper?S2414314618008660 |
work_keys_str_mv |
AT mouhamadoubiramediop factriaqua22bipyridinek2nnnitratokocobaltiichloride AT libassediop factriaqua22bipyridinek2nnnitratokocobaltiichloride AT sylvainbernes factriaqua22bipyridinek2nnnitratokocobaltiichloride |
_version_ |
1725505808056188928 |