4-Phenyl-1-[(1R,4R)-1,7,7-trimethyl-2-oxobicyclo[2.2.1]heptan-3-ylidene]hydrazinecarbothioamide
In the title compound, C17H21N3OS [common nomenclature: (R)-camphor 4-phenylthiosemicarbazone], the N—N—C—(S)—N fragment deviates slightly from planarity, with a maximum deviation of 0.0259 (12) Å for the hydrazinic N atom, and makes an angle of 29.55 (0)° with the aromatic ring. The molecular struc...
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doaj-d78cbc2965554c0ebe8b2edecd90775b2020-11-24T22:16:17ZengInternational Union of CrystallographyIUCrData2414-31462016-11-01111x16173010.1107/S2414314616017302bx40044-Phenyl-1-[(1R,4R)-1,7,7-trimethyl-2-oxobicyclo[2.2.1]heptan-3-ylidene]hydrazinecarbothioamideGabriela Porto de Oliveira0Leandro Bresolin1Vanessa Senna Nogueira2Priscila Jussiane Zambiazi3Adriano Bof de Oliveira4Escola de Química e Alimentos, Universidade Federal do Rio Grande, Av. Itália km 08, Campus Carreiros, 96203-900 Rio Grande-RS, BrazilEscola de Química e Alimentos, Universidade Federal do Rio Grande, Av. Itália km 08, Campus Carreiros, 96203-900 Rio Grande-RS, BrazilEscola de Química e Alimentos, Universidade Federal do Rio Grande, Av. Itália km 08, Campus Carreiros, 96203-900 Rio Grande-RS, BrazilDepartamento de Química, Universidade Federal de Santa Maria, Av. Roraima s/n, Campus Universitário, 97105-900 Santa Maria-RS, BrazilDepartamento de Química, Universidade Federal de Sergipe, Av. Marechal Rondon s/n, Campus Universitário, 49100-000 São Cristóvão-SE, BrazilIn the title compound, C17H21N3OS [common nomenclature: (R)-camphor 4-phenylthiosemicarbazone], the N—N—C—(S)—N fragment deviates slightly from planarity, with a maximum deviation of 0.0259 (12) Å for the hydrazinic N atom, and makes an angle of 29.55 (0)° with the aromatic ring. The molecular structure is stabilized by an intramolecular N—H...O hydrogen bond and a short N—H...N interaction with graph-set motifs S(6) and S(5), respectively. In the crystal, the centrosymmetric arrangement of the molecules resembles a herringbone packing motif along [001]. As a result of the steric effects of the camphor entity, an apolar organic periphery and the intramolecular nature of the hydrogen bonds, neither strong nor relevant intermolecular interactions are observed.http://scripts.iucr.org/cgi-bin/paper?S2414314616017302crystal structurecamphor derivativeherringbone packing motifchiral thiosemicarbazone derivative |
collection |
DOAJ |
language |
English |
format |
Article |
sources |
DOAJ |
author |
Gabriela Porto de Oliveira Leandro Bresolin Vanessa Senna Nogueira Priscila Jussiane Zambiazi Adriano Bof de Oliveira |
spellingShingle |
Gabriela Porto de Oliveira Leandro Bresolin Vanessa Senna Nogueira Priscila Jussiane Zambiazi Adriano Bof de Oliveira 4-Phenyl-1-[(1R,4R)-1,7,7-trimethyl-2-oxobicyclo[2.2.1]heptan-3-ylidene]hydrazinecarbothioamide IUCrData crystal structure camphor derivative herringbone packing motif chiral thiosemicarbazone derivative |
author_facet |
Gabriela Porto de Oliveira Leandro Bresolin Vanessa Senna Nogueira Priscila Jussiane Zambiazi Adriano Bof de Oliveira |
author_sort |
Gabriela Porto de Oliveira |
title |
4-Phenyl-1-[(1R,4R)-1,7,7-trimethyl-2-oxobicyclo[2.2.1]heptan-3-ylidene]hydrazinecarbothioamide |
title_short |
4-Phenyl-1-[(1R,4R)-1,7,7-trimethyl-2-oxobicyclo[2.2.1]heptan-3-ylidene]hydrazinecarbothioamide |
title_full |
4-Phenyl-1-[(1R,4R)-1,7,7-trimethyl-2-oxobicyclo[2.2.1]heptan-3-ylidene]hydrazinecarbothioamide |
title_fullStr |
4-Phenyl-1-[(1R,4R)-1,7,7-trimethyl-2-oxobicyclo[2.2.1]heptan-3-ylidene]hydrazinecarbothioamide |
title_full_unstemmed |
4-Phenyl-1-[(1R,4R)-1,7,7-trimethyl-2-oxobicyclo[2.2.1]heptan-3-ylidene]hydrazinecarbothioamide |
title_sort |
4-phenyl-1-[(1r,4r)-1,7,7-trimethyl-2-oxobicyclo[2.2.1]heptan-3-ylidene]hydrazinecarbothioamide |
publisher |
International Union of Crystallography |
series |
IUCrData |
issn |
2414-3146 |
publishDate |
2016-11-01 |
description |
In the title compound, C17H21N3OS [common nomenclature: (R)-camphor 4-phenylthiosemicarbazone], the N—N—C—(S)—N fragment deviates slightly from planarity, with a maximum deviation of 0.0259 (12) Å for the hydrazinic N atom, and makes an angle of 29.55 (0)° with the aromatic ring. The molecular structure is stabilized by an intramolecular N—H...O hydrogen bond and a short N—H...N interaction with graph-set motifs S(6) and S(5), respectively. In the crystal, the centrosymmetric arrangement of the molecules resembles a herringbone packing motif along [001]. As a result of the steric effects of the camphor entity, an apolar organic periphery and the intramolecular nature of the hydrogen bonds, neither strong nor relevant intermolecular interactions are observed. |
topic |
crystal structure camphor derivative herringbone packing motif chiral thiosemicarbazone derivative |
url |
http://scripts.iucr.org/cgi-bin/paper?S2414314616017302 |
work_keys_str_mv |
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